In this study, the swelling kinetics of individual tea particles as well as bed of tea granules were investigated for different types of teas. The swelling experiments involved image analysis and volume measurements of tea particles. Each individual particle shows different swelling characteristics. Separating funnels and cylindrical columns of varying sizes were used to study the changes in volume of tea bed. Swelling in separating funnel was observed to be more than that in column. The effect of temperature, particle size, bed height and vessel diameter were investigated. The extent as well as the rate of swelling is found to increase with rise in temperature (60 to 80 °C) and reduction in particle size. A decrease in swelling is observed with increase in bed height as well as decrease in vessel diameter and vice a versa. About 70 to 75 % swelling occurs in the first 40 to 45 s. Two empirical models viz. Weibull and Peleg were used to fit the experimental data. The rate parameters obtained for a sample T5 at different temperatures were in the range of 0.012 to 0.016. The volume changes of all the teas were compared with their elution behavior, by measuring the absorbance of a diluted sample of brew at 272 nm. The activation energies for the process of tea swelling calculated for T1 (1.2 mm), T5 (2.2 mm) and T5 (0.72 mm) were 14.156, 8.37 and 13.42 kJ/mol respectively.

Two different types of CTC (Crush, Tear and Curl) teas were used for infusion kinetics study. Infusion kinetics for these and their ground and sieved fractions were studied over a 15-min period at 60°C and 80°C. Samples were analyzed using UV-Vis spectroscopy. Results of infusion have been interpreted in terms of gallic acid equivalence (GAE). Fractions with smaller particle size show faster infusion. First-order rate constants for largest and smallest fractions were 0.257–0.685 min−1, respectively, at 60°C. A quasi-steady-state model was developed, which determines initial dissolution rate, diffusion rate from actual infusion rate and hence rate controlling step. At 80°C, the infusion rate of the 0.33 mm granules was found to be 98% of the dissolution rate as compared to 68% in case of 1.99 mm granules. The diffusivity values were found to be 2.23×10−10 m2/s and 4.34×10−10 m2/s at 60°C and 80°C, respectively.

The present study deals with swelling and infusion kinetics of tea granules in tea bags. The swelling and infusion kinetics of tea bags differing in tea loading and tea bag shapes were compared with loose tea. Increment in temperature and dipping frequency of tea bag in hot water increased the infusion kinetics of tea bags. Reduction in particle size enhanced the swelling and infusion kinetics of tea in a tea bag. The effects of tea particle size, tea bag dipping rate, loading of tea granules in tea bag and tea bag shapes on infusion kinetics were investigated. Increase in tea loading in tea bags resulted in reduced infusion kinetics. Double chambered tea bag showed the highest swelling (30%) and infusion kinetics (8.30% Gallic acid equivalence) while single chambered tea bags showed the lowest kinetics, amongst the various bags studied. The swelling and infusion kinetics of loose tea was always faster and higher than that of tea bags. It was found that overall effect of percentage filling of tea granules and height of tea bed in a tea bag affects tea infusion kinetics the most. Weibull model was found to be in good agreement with the swelling data.

The Wide-Area Linear Optical Polarimeter (WALOP)-South instrument is an upcoming wide-field and high-accuracy optical polarimeter to be used as a survey instrument for carrying out the Polar-Areas Stellar Imaging in Polarization High Accuracy Experiment (PASIPHAE ) program. Designed to operate as a one-shot four-channel and four-camera imaging polarimeter, it will have a field of view of 35 × 35 arcminutes and will measure the Stokes parameters I, q, and u in a single exposure in the SDSS-r broadband filter. The design goal for the instrument is to achieve an overall polarimetric measurement accuracy of 0.1 % over the entire field of view. We present here the complete polarimetric modeling of the instrument, characterizing the amount and sources of instrumental polarization. To accurately retrieve the real Stokes parameters of a source from the measured values, we have developed a calibration method for the instrument. Using this calibration method and simulated data, we demonstrate how to correct for instrumental polarization and obtain 0.1 % accuracy in the degree of polarization, p. Additionally, we tested and validated the calibration method by implementing it on a table-top WALOP-like test-bed polarimeter in the laboratory.

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