When metal nanoparticles are arranged
in an ordered array, they
may scatter light to produce diffracted waves. If one of the diffracted
waves then propagates in the plane of the array, it may couple the
localized plasmon resonances associated with individual nanoparticles
together, leading to an exciting phenomenon, the drastic narrowing
of plasmon resonances, down to 1–2 nm in spectral width. This
presents a dramatic improvement compared to a typical single particle
resonance line width of >80 nm. The very high quality factors of
these
diffractively coupled plasmon resonances, often referred to as plasmonic
surface lattice resonances, and related effects have made this topic
a very active and exciting field for fundamental research, and increasingly,
these resonances have been investigated for their potential in the
development of practical devices for communications, optoelectronics,
photovoltaics, data storage, biosensing, and other applications. In
the present review article, we describe the basic physical principles
and properties of plasmonic surface lattice resonances: the width
and quality of the resonances, singularities of the light phase, electric
field enhancement, etc. We pay special attention to the conditions
of their excitation in different experimental architectures by considering
the following: in-plane and out-of-plane polarizations of the incident
light, symmetric and asymmetric optical (refractive index) environments,
the presence of substrate conductivity, and the presence of an active
or magnetic medium. Finally, we review recent progress in applications
of plasmonic surface lattice resonances in various fields.
We studied the spectral evolution of plasmon modes associated with silver nanotriangles as a function of dielectric overlayer thickness in the range of 5-300 nm. A substantial red-shift of the resonance is observed that oscillates with increasing over-layer thickness. We explain this previously unreported oscillation through the cavity quantum electrodynamical effect of the array of triangles combined with the dielectric overlayer. The red-shift, though substantial, is less than expected. Comparison with numerical models indicates that this discrepancy is due to very tight field confinement around the tips of the triangles.
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