A mesoporous Mn-Co oxide for supercapacitors was derived from a mixed oxalate Mn<sub>0.8</sub>Co<sub>0.2</sub>C<sub>2</sub>O<sub>4</sub>·nH<sub>2</sub>O, which was synthesized by a solid-state coordination reaction at room temperature. The synthesized mixed Mn-Co oxalate was decomposed in air at 250°C, resulting in a tetragonal spinel Mn-Co oxide with a primary particle size less than 100 nm. The obtained Mn-Co oxide presents a mesoporous texture with a specific surface area of 120 m<sup>2</sup>·g<sup>﹣1</sup>. Electrochemical properties of the Mn-Co oxide electrode were investigated by cyclic voltammetry and galvanostatic charge/discharge in 6 mol·L<sup>﹣1</sup> KOH electrolyte. The Mn-Co oxide electrode delivered specific capacitances of 383 and 225 F·g<sup>﹣1</sup> at scan rates of 2 and 50 mV·s<sup>﹣1</sup>, respectively. Subjected to 500 cycles at a current density of 1.34 A·g<sup>﹣1</sup>, the symmetrical Mn-Co oxide capacitor showed specific capacitance of 179 F·g<sup>﹣1</sup>, still retaining ~85% of its initial capacitance. The obtained Mn-Co oxide material showed good capacitive performance, which was promising for supercapacitor applications
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