No abstract

Polymer complex fibers (PCFs) are a novel kind of fiber material processed from polymer complexes that are assembled through noncovalent interactions. These can realize the synergy of functional components and miscibility on the molecular level. The dynamic character of noncovalent interactions endows PCFs with remarkable properties, such as reversibility, stimuli responsiveness, self-healing, and recyclability, enabling them to be applied in multidisciplinary fields. The objective of this article is to provide a review of recent progress in the field of PCFs. The classification based on chain interactions will be first introduced followed by highlights of the fabrication technologies and properties of PCFs. The effects of composition and preparation method on fiber properties are also discussed, with some emphasis on utilizing these for rational design. Finally, we carefully summarize recent advanced applications of PCFs in the fields of energy storage and sensors, water treatment, biomedical materials, artificial actuators, and biomimetic platforms. This review is expected to deepen the comprehension of PCF materials and open new avenues for developing PCFs with tailor-made properties for advanced application.

No abstract

Stretchable optical diffuser is an indispensable photon management element in wearable display devices. Herein, a novel optical diffuser constructed by interfacial hydrogen bonding complexation of methylcellulose (MC), poly(ethylene oxide) (PEO), and polymer complex nanoparticles (PCNP) on transparent polydimethylsiloxane (PDMS) substrate is proposed. The introduction of PEO can toughen the complex film and endow the coating with stretchability. With proper thermal treatment, the polymer complex can be crosslinked through esterification which shows an improved optical diffusion performance and durability. The optimized film exhibits 92% of transmittance (T), 93% of haze (H), and 73% of elongation. It also presents a desirable optical diffusion effect about 88% of T and 93% of H in the stretching state. Moreover, the resulting complex film shows excellent anti‐fatigue capacity which maintains 90% of T and 90% of H after 10 000 stretching cycles. The reported polymer complex film broadens the application of interfacial complexation and demonstrates potential to apply in the integrated wearable optical devices.

Elastomers with environmental adaption have attracted considerable attention for advanced applications in various areas. Here, we fabricate an ambient environment adaptive elastomer by assembling triblock copolymers polystyrene-b-poly(acrylic acid)b-polystyrene (SAS) and polystyrene-b-poly(ethylene oxide)-bpolystyrene (SES). Owing to the microphase separation of triblock polymers and hydrogen-bonding complexation of their middle segments, the SAS/SES complex presents dichotomy of vitrified hard PS domains and soft PAA/PEO domains, which presents major relaxation transition in the temperature zone 10−30 °C and relative humidity (RH) 40−60%. The SAS/SES elastomer presents quick adaption to the ambient environment change with temperature and humidity coupling. Moreover, after a loading-unloading cycle training, the SAS/SES elastomer exhibits domain orientation, low energy dissipation, high recovery ratio, and distinct strain stiffening compared with the pristine complex. The SAS/SES elastomer has potential to be used as a sensing and adaption component for complicated intelligent systems.