The objective of this work was to valorize the clays of Côte d'Ivoire in the treatment of wastewater. The study focused on the ability of raw clays from Bouaflé city to adsorb methylene blue and cadmium ions, in aqueous solution. The physicochemical characteristics of the clay were determined using the measurement of its specific surface area, chemical analysis and mineralogical analysis. It emerges from these characterizations that clay is essentially composed of type 2/1 minerals such as illite (32.94%), type 1/1 kaolinite (8.47%), quartz (40.23 %) and approximately iron oxy-hydroxides (18.36%). Its specific surface is 37.58 m2 / g. The kinetics, thermodynamics and isotherms of adsorption have been used to understand the mechanism of adsorption. The results obtained show that the organic pollutant alone in solution (methylene blue (MB)) is adsorbed quite quickly. We obtained a decoloration yield greater than 90% after 40 min of adsorbate-adsorbent contact. The elimination of methylene blue is greater in a basic medium. The BM adsorption kinetics were modeled. The comparison of the correlation factors of the different kinetic models used has shown that the adsorption kinetics of the organic pollutant (MB) better match the pseudo second order kinetic model. Thermodynamics predicted a spontaneous endothermic surface reaction, due to the positive sign of and the negative sign of , obtained ( = 31.398; = -12.635). Analysis of adsorption isotherms allowed us to show that the adsorption of methylene blue on clay is physisorption type and in monolayer. The experiments were also performed with an aqueous solution containing both methylene blue and cadmium ions. After a contact time of 120 min, 60% of the cadmium ions are adsorbed on the clay against only 20% of methylene blue. Thus, clay preferentially eliminates trace metal elements (Cd2+) compared to organic pollutants (methylene blue).
The use of antimicrobials without microbiological proof is frequent and contributes to the emergence of resistance. The aim was to identify the organisms isolated during laboratory examinations and the type of antimicrobials consumed by patients hospitalized to Infectious Diseases' Clinic. This is a cross-sectional and analytical study, carried out from January 1 to December 31, 2017 in the Infectious Diseases Department of Point "G" Teaching Hospital in Mali. All biological specimens from patients during the study period were analyzed. In total, 322 patients benefited from microbiological test, with a mean age of 40.9 ± 12.2 years (range 15 and 74 years) with a sex ratio of 0.93. Only 5.6% of patients were HIV negative. In all participants, a total of 658 microbiological specimen were taken, 224 (34.0%) identified at least one pathogen including bacteria in more than a half of the cases (58.5%). On the report of bacteriological analysis, the most frequently identified organisms were Mycobacterium tuberculosis (42.2%) mainly in sputum; Escherichia coli (24.2%) and Klebsiella pneumoniae (7.8%) commonly in urine and Gardnerella vaginalis (7.0%) exclusively in vaginal secretions. Candida albicans (5/8) and Cryptococcus neoformans (3/8) were the most common fungi while Plasmodium falciparum (96.4%
Background: Fahr syndrome associates a set of neuropsychiatric manifestations with bilateral calcifications in the basal ganglia and phosphocalcic disorders. Neuromeningeal cryptococcosis can be present in its manifestations, neuropsychic disorders with or without meningeal signs. The objective was to describe a rare association between Fahr syndrome and neuromeningeal cryptococcosis which can be expressed by the same clinical symptomatology in the context of co-infection with the human immunodeficiency virus (HIV) and the hepatitis B virus (HBV). Presentation: A 37-year-old patient without pathological history, who presented behavioral disorders that led to a fight with those around her and a psychiatric consultation. Then, she was hospitalized in the infectious diseases Department upon discovery of her HIV status and viral hepatitis B. She was logorrheic with behavioral disturbances and subsequently presented with tonic-clonic convulsions. Laboratory tests and imaging have concomitantly discovered Fahr syndrome due to pseudohypoparathyroidism and neuromeningeal cryptococcosis. The correct management of these two pathologies enabled stabilization of the patient's clinical condition with regular monitoring for HIV-HBV coinfection. Conclusion: Farh syndrome and neuromeningeal cryptococcosis are two different entities but sometimes similar symptoms and risk factors. Treatment of metabolic disorders combined with anticryptococcal therapy improved the prognosis.
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