In this study, a poly(lactic acid) (PLA) ternary blend system consisting of PLA, an epoxycontaining elastomer, and a zinc ionomer was introduced and studied in detail. Transmission electron microscopy revealed that the "salami"-like phase structure was formed in the ternary blends. While increase in blending temperature had little effects on the tensile properties of the resulting blends, it greatly changed the impact strength. For the blends prepared at 240 °C by extrusion blending, the resulting PLA ternary blends displayed supertoughness with moderate levels of strength and modulus. It was found that the zinc ions catalyzed the cross-linking of epoxy-containing elastomer and also promoted the reactive compatibilization at the interface of PLA and the elastomer. Both blending temperature and elastomer/ionomer ratio were found to play important roles in achieving supertoughness of the blends. The significant increase in notched impact strength was attributed to the effective interfacial compatibilization at elevated blending temperatures.
Recent progress on the preparation and surface characteristics of polymeric anti-icing coatings from low surface energy or liquid-infused slippery surfaces is reviewed and illustrated.
Ice accretion poses a severe impact on diverse aspects of human life. Although great efforts have been dedicated to prevent or alleviate ice adhesion to the surface of substrates by developing various icephobic coatings, it is still needed to improve the integrated performance. Herein, we present a novel strategy to prepare poly(dimethylsiloxane) (PDMS) slippage coatings by combining a soft architecturedriven branched PDMS with partial short PDMS-functionalized polyhedral oligomeric silsesquioxane (POSS) as a cocross-linker, in which silicone oil with certain viscosity was added as a lubricant. The chemical structure, surface morphology, and icephobic durability of the prepared coatings were investigated with concerns for the potential anti-icing uses. The PDMS slippage coating shed light on extraordinary icephobic durability with the ice shear strength at approximately 11.2 kPa and maintained low values below 14 kPa even after 50 icing/deicing cycles. Due to the elaborate control of the crosslink density, the side chains of the branched PDMS provided a rich storage space for entrapped silicone oil for the formation of the interfacial slippage. Moreover, the introduction of the functionalized POSS brought about significantly improved mechanical resistance in abrasion and elastic modulus. It is suggested that the branched PDMS slippage coating is a promising candidate in practical anti-icing applications.
Functional electrospun membranes loaded with Dex-g-PLL-VAPG/miR-145 complexes exhibit the excellent ability to modulate SMC phenotype and proliferation locally.
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