In conventional process of ceramic injection molding, wax‐based binders could only be removed by thermal or organic solvent debinding. Recently, water solvent debinding has appeared as a good alternative owing to its high efficiency and environmental friendliness. In present work, we have demonstrated the surface modification mechanism of stearic acid (SA) to zirconia powders induced by a prior ball‐milling treatment before the blending process. Layers of SA with various thicknesses coated around the zirconia powders have been achieved with different amount of SA after the treatment, agreeing well with the theoretically calculated values. The coating is disclosed to be an esterification occurring between the carboxyl group of SA and hydroxyl group of zirconia surface. It plays an important role in limiting agglomeration of ceramic powders and changing the nature of powder surface from hydrophilicity to hydrophobicity, which decreases the shear viscosity of the feedstock and makes the water‐debound compact process‐compatible with few phase separation. In addition, a significantly faster water‐debinding rate was obtained.
Summary
Because of the widespread application of new energy and power electronic–based residential loads in distribution networks, the impact of collective harmonics cannot be ignored. The harmonic impedance should be evaluated when determining the harmonic responsibilities at the point of common coupling. This paper presents a new noninvasive method to quantify the harmonic current responsibilities of the utility side and customer side on the basis of impedance‐gathering trend. The method is compared with another noninvasive resistance‐sign–based method. In addition, the emission level of the residential loads is calculated. The presented results of a field test conducted in a typical residential apartment in Shanghai, China, prove that the method works well in practical conditions.
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