The plasma-driven gas-phase thermal decomposition of methane yielding hydrogen and solid-phase carbon has been suggested as an environmentally friendly alternative to conventional methods of producing hydrogen from natural gas. The advantage of the process is that hydrogen is obtained directly from methane without producing CO2 as a byproduct. The process was experimentally examined using a modified version of a dc plasma reactor originally developed for the conversion of methane to acetylene. Carbon yields of 30%, a factor of 6 increase, with a corresponding decrease in acetylene yield were obtained by simply increasing the residence or reaction time. A detailed kinetic model that includes the reaction mechanisms resulting in the formation of acetylene and heavier hydrocarbons through benzene is described. A model for solid carbon nucleation and growth is included. The model is compared to experimental results and is used to examine process optimization.

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The performance and capacity of Kraft recovery boilers is sensitive to black liquor velocity, droplet size and flow distribution in the furnace. Studies have shown that controlling droplet size and flow distribution improves boiler efficiency while allowing increased flight drying and devolatilization, and decreased carryover. The purpose of this study is to develop a robust two-phase numerical model to predict black liquor splashplate nozzle spray characteristics. A three-dimensional time dependent numerical study of black liquor sheet formation and sheet breakup is described. The volume of fluid (VOF) model is used to simulate flow through the splashplate nozzle up to initial sheet breakup and droplet formation. The VOF model solves the conservation equations of volume fraction and momentum utilizing the finite volume technique. Black liquor velocity, droplet size and flow distribution over a range of operating parameters are simulated using scaled physical models of splashplate nozzles. The VOF model is compared to results from a flow visualization experiment and experimental data found in the literature. The details of the simulation and experimental results are presented.

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