Rare earth barium copper oxide (REBCO) coated conductor has emerged as one of the high T
c superconductors suitable for future ultrahigh field superconducting magnet applications. In the design and fabrication of such ultrahigh field REBCO magnets, it is essential to understand the behavior of REBCO coated conductor. The effect of heating on the properties of commercial REBCO coated conductors is very important for many practical reasons. Nevertheless, a comprehensive study on this effect have not yet been presented in the published literature. This work studies a commercial REBCO coated conductor heat-treated at temperatures between 175 °C and 300 °C for various durations. Critical current and lap joint resistivity were measured at 77 K and 4.2 K for the heat-treated samples. We found that critical current degrades with heat treatment time and temperature. This degradation can be described by a one-dimensional oxygen out-diffusion model with a diffusion coefficient of D = 2.5 × 10−6 exp (−1.17eV kT−1) m2 s−1. The heat treatment also causes appreciable increase in joint resistivity. Comprehensive structural and chemical analyses were performed on Cu/Ag/RECBO interfaces by transmission electron microscopy. Our electron energy loss spectroscopy study provided direct evidence of oxygen deficiency in the heat treated REBCO samples. In addition, it is found that the oxygen diffused out of the REBCO layer forms mostly Cu2O at both Ag/REBCO and Cu/Ag interfaces. Cu2O is also observed at grain boundaries of the Ag layer. The oxygen out-diffusion model proposed in this work is used to predict REBCO thermal degradation in several engineering scenarios.
Advances on no-insulation REBCO coil technology has made understanding and controlling contact resistivity increasingly important. Praffin (wax) impregnation is a process that has been used for improving mechanical stability of insulated and no-insulation REBCO coils. Wax impregnation is beneficial in both no-insulation coils and insulated coils with additional copper stabilizer or multiple conductors. In the latter scenario, contact resistance between conductor and additional stabilizer is also important. It is crucial to understand the effects of wax impregnation on contact resistivity (Rct). We designed and built an apparatus to use short REBCO samples which simulates the behavior of Rct in a pancake coil during the wax impregnation process. Rct was measured at 77 K before and after the wax impregnation. In addition, a single pancake coil was wound to test the effect of wax impregnation. This coil simulates the NHMFL 32 T magnet Coil A in winding stresses. Rct was measured at 77 K and 4.2 K before and after wax impregnation. We found that wax impregnation does not significantly change contact resistivity. This means that wax impregnation can be used in coils without compromising the current sharing ability between turns. The experimental process and results are discussed.
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