A rapid growth of textile industry creates a new problems on environment, one of those is the presence of dye waste. Methylene blue is one of the dyes which is toxic to living things, one of those triggers cyanosis for human and bother photosyntesis of algae. Therefore, it needs the effort to reduce, one of those is by adsorption. This study aims to determined the effect of dosage adsorbent variation and contact time variation to adsorb methylene blue. Adsorption is an adsorbate molecule absorption process that occurs on the surface of the adsorbent. This study used fly ash from PG. Pagottan and has been activated by NaOH. Measure method of this study using UV-Vis Spectrophotometry to measure concentration of methylene blue at maximum wavelenght. Based on data, NaOH-activated fly ash and non-activated fly ash following Langmuir isotherm adsorption, it mean a monolayer site is formed. Adsorption capacity also increase after activation, it about 21,74 mg/g to 23, 25 mg/g. Based on the study fly ash has a potential as a new adsorbent.
Biodiesel is synthesized from the trans-esterification reaction of vegetable oil and alcohol using a catalyst such as acids, bases or enzymes. The acid catalyst that is often used is sulfuric acid; H2SO4, and HCl while most of base catalysts are NaOH and KOH. The aim of this study is to determine the effect of carbon derived from sugar heating in the synthesis of biodiesel with a sulfuric acid catalyst; H2SO4. Trans-esterification reaction of Jatropha oil and methanol with sulfuric acid catalyst was done with oil and methanol at 1:9 ratio. The results showed that (1) the physical properties of the biodiesel was synthesized with carbon-H2SO4 has a difference with physical properties the biodiesel was synthesized by sulfuric acid (2) carbon-H2SO4 was used in the trans-esterification reaction of Jatropha oil and methanol to produce methyl ester character is the density of 0.889 g / mL, 24.59 cSt viscosity and refractive index of 1.464, (3) methyl ester produced from the reaction of trans-esterification of Jatropha oil and methanol with sulfuric acid catalyst has a character that is a density of 0.882 g / mL, 11.70 cSt viscosity and refractive index of 1.458.
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