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Nitric oxide formation in gas turbine combustion depends on four key factors: flame stabilization, heat transfer, fuel–air mixing and combustion instability. The design of modern gas turbine burners requires delicate compromises between fuel efficiency, emissions of oxides of nitrogen (NOx) and combustion stability. Burner designs allowing substantial NOx reduction are often prone to combustion oscillations. These oscillations also change the NOx fields. Being able to predict not only the main species field in a burner but also the pollutant and the oscillation levels is now a major challenge for combustion modelling. This must include a realistic treatment of unsteady acoustic phenomena (which create instabilities) and also of heat transfer mechanisms (convection and radiation) which control NOx generation.In this work, large-eddy simulation (LES) is applied to a realistic gas turbine combustion chamber configuration where pure methane is injected through multiple holes in a cone-shaped burner. In addition to a non-reactive simulation, this article presents three reactive simulations and compares them to experimental results. The first reactive simulation neglects effects of cooling air on flame stabilization and heat losses by radiation and convection. The second reactive simulation shows how cooling air and heat transfer affect nitric oxide emissions. Finally, the third reactive simulation shows the effects of combustion instability on nitric oxide emissions. Additionally, the combustion instability is analysed in detail, including the evaluation of the terms in the acoustic energy equation and the identification of the mechanism driving the oscillation.Results confirm that LES of gas turbine combustion requires not only an accurate chemical scheme and realistic heat transfer models but also a proper description of the acoustics in order to predict nitric oxide emissions and pressure oscillation levels simultaneously.

This paper deals with the dynamics of standing and rotating azimuthal thermoacoustic modes in annular combustion chambers. Simultaneous acoustic measurements have been made at multiple circumferential positions in an annular gas turbine combustion chamber. A detailed statistical analysis of the spatial Fourier amplitudes extracted from these data reveals that the acoustic modes are continuously switching between standing, clockwise and counter-clockwise travelling waves. A theoretical framework from which the modal dynamics can be explained is proposed and supported by real gas turbine data. The stochastic differential equations that govern these systems have been derived and used as a basis for system identification of the measured engine data. The model describes the probabilities of the two azimuthal wave components as a function of the random source intensity, the asymmetry in the system and the strength of the thermoacoustic interaction. The solution of the simplified system is in good agreement with experimental observations on a gas turbine combustion chamber.

An experimental method to determine the thermoacoustic properties of a gas turbine combustor using a lean-premixed low emission swirl stabilized burner is presented. To model thermoacoustic oscillations, a combustion system can be described as a network of acoustic elements, representing for example fuel and-air supply, burner and flame, combustor, cooling channels, suitable terminations, etc. For most of these elements, simple analytical models provide an adequate description of their thermoacoustic properties. However, the complex response of burner and flame (involving a three-dimensional flow field, recirculation zones, flow instabilities and heat release) to acoustic perturbations has -at least in a first step -to be determined by experiment. In our approach, we describe the burner as an active acoustical two-port, where the state variables pressure and velocity at the inlet and the outlet of the two port are coupled via a four element transfer matrix. This approach is similar to the "black box" theory in communication engineering. To determine all four transfer matrix coefficients, two test states, which are independent in the state vectors, have to be created. This is achieved by using acoustic excitation by loudspeakers upstream and downstream of the burner, respectively. In addition, the burner might act as an acoustic source, emitting acoustic waves due to an unsteady combustion process. The source characteristics were determined by using a third test state, which again must be independent from the two other state vectors. In application to a full size gas turbine burner, the method's accuracy was tested in a first step without combustion and the results were compared to an analytical model for the burner's acoustic properties. Then the method was used to determine the burner transfer matrix with combustion. An experimental swirl stabilized premixed gas-turbine burner was used for this purpose. The treatment of burners as acoustic two-ports with feedback including a source term and the experimental determination of the burner transfer matrix is novel. NOMENCLATURE