The
integration of nanometer-sized fillers into polymer matrices
to create nanocomposite materials has attracted a great deal of interest,
not only because these materials can be tailored to specific practical
applications but also because they can exhibit synergistic combinations
of properties that display multifunctionality. Herein, we successfully
incorporated silica (SiO2) nanoparticles into the rubber-modified
polybenzoxazine (PBZ) by mixing and applied as a nanocomposite coating
that exhibits both superhydrophobicity and superoleophilicity through
a facile dipping and spraying technique. We used PBZ, not only because
of its near-zero shrinkage upon polymerization, chemical resistance,
and good dielectric, thermal, and mechanical properties but also because,
most importantly, of its low surface free energy and low water absorptivity.
With superhydrophobicity coexisting with superoleophilicity in one
material, potential anticorrosion, anti-ice, and organics/water separation
applications of the coating were investigated. Results revealed that
the rubber-modified PBZ coating with the optimum SiO2 loading
was able to display superior antiwettability and anticorrosion performance
even during prolonged exposure to corrosive environment. The coating
also showed promising anti-icing ability by preventing ice/snow from
adhering to the surface and delaying icing of water upon striking
the surface. Furthermore, when our coating was applied onto a metal
mesh, the resulting coated membrane was able to effectively separate
dichloromethane (DCM), a nonpolar oil, from water. Combined with good
thermal and adhesion properties, the existence of all the aforementioned
properties makes the developed nanocomposite a very promising coating
material for multifunctional application purposes.
This work reports a simple approach to prepare toughened 3D‐printed polymethacrylate (PMA) composites using surfactant‐modified chitosan (SMCS) particles at loadings between 2–10 wt%. Chitosan (CS) is modified with anionic surfactant, sodium dodecyl sulfate, via ionic complexation to facilitate compatibility and dispersion of CS to PMA matrix by non‐covalent interactions between the components. The study successfully demonstrates high‐accuracy 3D printing of composites with significant improvements in the overall mechanical properties. The composite with the best loading of 8 wt% SMCS shows a tensile modulus of 1.23 ± 0.05 GPa, a tensile strength at 49.8 ± 0.96 MPa, a yield stress at 33.3 ± 1.48 MPa, and a strain‐at‐failure 10.3 ± 0.61%, which are 45%, 40%, 32%, and 68% higher than neat PMA, respectively. This provides a significant improvement in toughness at 4.92 ± 0.55 MJ m−3 for the composite, 184% higher than that of neat PMA. The marked increase in toughness is due to enhanced filler‐matrix interactions which improve the ability of the 3D printed composite to absorb energy under tensile load. The results from this work provide new understandings into the strategies for design and preparation of stereolithography 3D printed materials reinforced with toughening fillers from renewable resources.
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