Perfect single grains of the AlPdMn icosahedral phase have been used for structure determination by X-ray and neutron diffraction. Owing to the large difference between X-ray and neutron scattering factors, information is gained on the atomic positions of the three elements. A model is proposed as deduced from a six-dimensional (6D) Patterson analysis. Six different atomic hypersurfaces are located on node and body-centre sites of the 6D lattice. The superstructure that leads to a face-centred lattice is mainly due to a strong chemical ordering, all the palladium being on the even node and odd body centre of the 6D cube. The resulting 3D structure contains icosahedral clusters similar to the external shell of the Mackay icosahedron, with two kinds of chemical decoration. The structure may also be described via a quasi-periodic stacking of fivefold planes. Each set of planes is characterized by an average chemical composition and local order. This kind of description helps in the understanding of quasi-crystal growth, formation of dislocations and dynamic properties.

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Upon substituting Ca for Eu in the local-moment ferromagnet EuB6, the Curie temperature T(C) decreases substantially with increasing dilution of the magnetic sublattice and is completely suppressed for x

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