[1] Phyllosilicates on Mars mapped by infrared spectroscopic techniques could have been affected by dehydration and/or dehydroxylation associated with chemical weathering in hyperarid conditions, volcanism or shock heating associated with meteor impact. The effects of heat-induced dehydration and/or dehydroxylation on the infrared spectra of 14 phyllosilicates from four structural groups (kaolinite, smectite, sepiolite-palygorskite, and chlorite) and two natural zeolites are reported here. Pressed powders of size-separated phyllosilicate and natural zeolite samples were heated incrementally from 100°C to 900°C, cooled to room temperature, and measured using multiple spectroscopic techniques: midinfrared (400-4000 cm −1 ) attenuated total reflectance, midinfrared reflectance (400-1400 cm −1 ), and far-infrared reflectance (50-600 cm −1 ) spectroscopies. Correlated thermogravimetric analysis and X-ray diffraction data were also acquired in order to clarify the thermal transformation of each sample. For phyllosilicate samples, the OH stretching (∼3600 cm −1 ), OH bending (∼590-950 cm −1 ), and/or H 2 O bending (∼1630 cm −1 ) bands all become very weak or completely disappear upon heating to temperatures > 500°C. The spectral changes associated with SiO 4 vibrations (∼1000 cm −1 and ∼500 cm −1 ) show large variations depending on the compositions and structures of phyllosilicates. The thermal behavior of phyllosilicate IR spectra is also affected by the type of octahedral cations. For example, spectral features of Al 3+ -rich smectites are more stable than those of Fe 3+ -rich smectites. The high-temperature (>800°C) spectral changes of trioctahedral Mg 2+ -rich phyllosilicates such as hectorite, saponite, and sepiolite result primarily from crystallization of enstatite. Phyllosilicates with moderate Mg 2+ concentration (e.g., palygorskite, clinochlore) and dioctahedral montmorillonites (e.g., SAz-1 and SCa-3) with partial Mg 2+ -for-Al 3+ substitution all have new spectral feature developed at ∼900 cm −1 upon heating to 800°C. Compared with phyllosilicates, spectral features of two natural zeolites, clinoptilolite and mordenite, are less affected by thermal treatments. Even after heating to 900°C, the IR spectral features attributed to Si (Al)-O stretching and bending vibration modes do not show significant differences from those of unheated zeolites.
Chloride salt‐bearing deposits on Mars were discovered using the Mars Odyssey Thermal Emission Imaging System (THEMIS) and have been characterized by both mid‐infrared (MIR) and visible‐to‐near‐infrared (VNIR) remote sensing instruments. The chloride salt‐bearing deposits exhibit a blue slope at MIR wavelengths and a featureless red slope at VNIR wavelengths. These deposits also lack strong 3 µm bands in VNIR spectra, indicating that they are desiccated compared to the surrounding regolith. The lack of VNIR spectral features suggests that an anhydrous chloride salt, the most likely of which is halite, is responsible for the observed spectral slope. In this work, we use laboratory spectra and a hybrid T‐matrix/Hapke light scattering model to constrain the particle sizes and salt abundances of the Martian chloride salt‐bearing deposits. Our work shows that the two broad spectral classes of these deposits observed by THEMIS can be explained by a difference in the particle size of the admixed silicate regolith. In all cases, chloride salt abundances of 10–25% are required to match the THEMIS data. The chloride salt abundances determined in this work suggest deposition in a lacustrine/playa setting or in association with late‐stage groundwater upwelling.
Previous laboratory analyses have shown that high temperatures can modify the crystal structures of some phyllosilicates in such a way that their spectroscopic signatures appear different from various wavelength perspectives. This may be the case in the Nili Fossae region of Mars, where our analyses indicate that thermally altered (~400°C) Fe-rich smectites might be possible mineral analogs to the phyllosilicate-bearing units in addition to mineral assemblages formed by Fe/Mg smectite and amorphous weathering products. We suggest that thermal alteration of phyllosilicates induced by impact shock or other heat sources might be a widespread process throughout Martian history. The mixing of altered and unaltered phyllosilicates might be partially responsible for the apparent disconnect between VNIR and TIR observations of Fe/Mg smectite-bearing surfaces on Mars.
PurposeThrough this research study, the authors found that digital thread has made significant progress in the life cycle management of the US Air Force. The authors hope that by reviewing similar studies in the aerospace field, the meaning of digital thread can be summarized and applied to a wider range of fields. In addition, theoretically, the definition of digital twin and digital thread are not unified. The authors hope that the comparison of digital thread and digital twin will better enable scholars to distinguish between the two concepts. Besides, the authors are also looking forward that more people will realize the significance of digital thread and carry out future research.Design/methodology/approachComplete research about digital thread and the relevant concept of the digital twin is conducted. First, by searching in Google Scholar with the keyword “digital thread”, the authors filter results and save literature with high relevance to digital thread. The authors also track these papers’ references for more paper of digital thread and digital twin. After removing the duplicate and low-relevance literature, 72 digital thread-related literature studies are saved and further analyzed from the perspective of time development, application field and research directions.FindingsDigital thread application in industries other than the aviation manufacturing industry is still relatively few, and the research on the application of digital thread in real industrial scenarios is mainly at the stage of framework design and design-side decision optimization. In addition, the digital thread needs a new management mechanism and organizational structure to realize landing. The new management mechanism and the process can adapt to the whole life cycle management process based on the digital thread, manage the data security and data update, and promote the digital thread to play a better effect on the organizational management.Practical implicationsBased on a review of digital thread, future research directions and usage suggestions are given. The fault diagnosis of high-speed train bogie as an example shows the effectiveness of the method and also partially demonstrates the advantages and effects brought by the digital thread connecting the data models at various stages.Originality/valueThis paper first investigates and analyzes the theoretical connotation and research progress of digital thread and gives a complete definition of digital thread from the perspective of the combination of digital thread and digital twins. Next, the research process of digital thread is reviewed, and the application fields, research directions and achievements in recent years are summarized. Finally, taking the fault diagnosis of high-speed train bogie as an example partially demonstrates the advantages and effects brought by the digital thread connecting the data models at various stages.
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