In many nations industrial scale AD of non-agricultural waste materials (such as MSW) has not yet reached its full potential, often constrained by the lack of secure, inexpensive, high quality AD feedstocks, and markets for the resulting digestate material. We tested the output material of a high throughput novel industrial process to define its potential as an AD feedstock (based on quality and consistency). This process, designed to circumvent the constraints of source segregation while still generating segregated waste streams, resulted in the production of a temporally homogenous fibrous material with: an average moisture content of 44.2 (±2.33)%; C:N ratio of ∼32.9:1 (±3.46:1), C:P ratio of ∼228:1 and gross calorific value of 17.4 (±0.29)MJ/kg. This material provided a CH yield of between 201 and 297m CH/tonne (271-401mCH/tonne) comparable to commonly used AD feedstocks. Material contaminant levels were temporally consistent (P>0.05), (average values being Cd 0.63 (±0.19), Cu 56.3 (±7.45), Cr 51.4 (±4.41), Hg<0.3, Ni 28.9 (±5.17), Pb 79.2 (±23.71), Zn 202 (±44.5), total polyaromatic hydrocarbons (PAH) 2.2 (±0.3), and total polychlorinated biphenyls (PCB) (<0.2)mg/kg). Calculated digestate contaminant levels were below the median contaminant threshold limits for anaerobic digestates of all countries within the European Union i.e. of Cd 3.35, Cu 535, Cr 535, Hg 8.15, Ni 185, Pb 397.5, Zn 2100mg/kg. We suggest that novel high throughput processes that produce high quality AD feedstocks, may have a place in further diversion of waste from landfill.

Ongoing research effort is dedicated to the development of innovative, superior and cost-effective ground improvement techniques to mitigate natural and man-made hazards while minimising waste and other environmental impacts. In this context, the nature-based process of biocementation of soils has been proposed as a potentially more sustainable technique than conventional chemical ground improvement practices. This paper focuses on the biocementation of an organic soil of the UK railway network. Having recently proven the feasibility of biocementing this soil using indigenous ureolytic bacteria, in this paper, the authors perform a parametric study to identify treatments successful in increasing the strength of the soil. Selected treatments are then applied to the soil to assess its volume change during consolidation, secondary compression and shrinkage upon drying. The results show that, depending on the treatments used, biocementation has increased the unconfined compressive strength by up to 81% compared to that of the control samples. For selected treatments and the range of water contents tested (55–33%), shrinkage upon drying reduced by 16%, while the volumetric strains of the soil upon 1-D compression reduced by 32–47%. This was reflected in the values of the coefficient of volume compressibility and the coefficient of secondary compression (the latter either reduced by up to an order of magnitude or secondary compression was not observed altogether in the testing period). Overall, the results proved that biocementation improved considerably the mechanical properties of the organic soil, which gives promise for addressing the settlement problems of this soil.

This paper assesses comparatively the performance of a number of innovative soil stabilisers for the treatment of a highly swelling-shrinking soil, against that of commercial calcium lime. The production of lime, a most common soil stabiliser, involves high energy consumption, carbon dioxide emissions and the depletion of natural raw materials. Alternatives are actively sought, in particular industrial wastes and by-product materials or lower energy demand cements e.g. reactive magnesia (MgO) cements. In this paper calcium lime, reactive magnesia, industrial wastes and mixes of these with lime are comparatively assessed, based on a number of conventional measures of the propensity of a soil to swell, i.e. plasticity characteristics and swelling characteristics (swelling strains, swelling pressures, swelling indices). Furthermore, as expansive soils are typically in an unsaturated state hence sensitive to both changes in water content and suction, filter paper testing was performed to provide additional evidence of the effect of the treatments on the swelling/shrinking soil. According to the main findings, for the treatment of swelling shrinking soils, binders coming from the paper recycling industry show most promise as alternatives to lime; reactive magnesia cement had a smaller effect than calcium based stabilisers in improving the swelling-shrinking of the soil, yet it also suppressed swelling and shrinkage considerably; it thus shows potential for use as an alternative to common soil stabilisers (Portland cement and calcium lime) to alleviate the environmental impact of the latter.

In the context of sustainability in the civil engineering industry, chemical ground improvement is becoming increasingly used, as a generally more sustainable alternative to replacing and landfilling unsuitable for construction ground. However, traditional soil stabilisers such as Portland cement or lime are not environmentally impact-free; international research effort is thus focusing on the development of innovative cementing agents. This paper presents results from a feasibility study on the development of suitable alkali-activated slag cements for the stabilisation of two soils. A number of alkali-activators were considered, comprising potassium hydroxide, a range of alkali salts, as well as a material retrieved from waste (Paper Sludge Ash, PSA) which contains free lime. Indicative results of an extensive parametric study in terms of unconfined compressive strength (UCS) are shown, followed by results of ongoing oedometer tests to determine soil compressibility and some preliminary tests on selected soil/binder mixes to observe the durability to wetting-drying cycles. Overall, all alkali-activated cement mixes increased the UCS and stiffness of the soil. Carbonates and Na2SiO3 used on their own gave lower strength increases. The highest strengths were achieved from AAC with KOH and Ca(OH)2 from PSA, which showed similar strength gain. The latter material has shown consistently a lot of promise in terms of strength, stiffness and volumetric stability of the soil as well as treatment durability. Ongoing research focuses on further mix optimisation and a comprehensive mechanical and durability property testing supported by material analysis (mineralogical, chemical and microstructural) to gain a better understanding of the complex mechanisms involved.

The stabilization of sulphate-bearing soils with traditional calcium-based stabilisers is not recommended, as reactions between the calcium and sulphates in the presence of water could lead to soil heave. Alternative stabilization methods are therefore required, and this paper proposes innovative alkali-activated cements (AAC), whose use for soil stabilisation and especially sulphate-bearing soils is little researched. To fill this knowledge gap, AAC systems with ground granulated blastfurnace slag precursor and different alkaline activators including commercial lime, wastepaper sludge ash (PSA), potassium hydroxide (KOH) and potassium carbonate (K 2 CO 3 ) were used to treat an artificial sulphate-bearing clay. AAC-treated clay specimens cured for 7 and 28 days respectively were soaked in water for 45 days; their one-dimensional swelling, unconfined compressive strength, pH, and ultrasonic pulse velocity were measured and compared to those of specimens not exposed to water. Material characterisation (SEM-EDS, Raman spectroscopy and FTIR) was performed to attest cementation and detect ettringite. In AAC systems, CaO/Ca(OH) 2 did not lead to specimen heave and damage and developed the highest strengths. Potassium-based activators performed less well but combined PSA-K 2 CO 3 led to strength gain in time. Overall AAC led to higher strengths than lime only or lime and admixtures and show promise as sulphate-bearing soil stabilisers. Thematic collection: This article is part of the Leading to Innovative Engineering Geology Practices collection available at: https://www.lyellcollection.org/topic/collections/leading-to-innovative-engineering-geology-practices