When polyethylene (PE) is deformed to large strains, the stress originates from both the
viscous forces associated with the plastic deformation of the crystallites by slip and fragmentation processes
and the entropic elastic forces arising from the stretching of the entangled amorphous regions. Relative
weights of the different processes change with the crystallinity. The dependencies were analyzed in a
comprehensive study on a series of samples encompassing a large range of crystallinities: PE, low-density
PE (LDPE), and ethylene−vinylacetate copolymers. The comparison was based on measured true stress−strain curves for constant strain rates. For the samples with higher crystallinity, which show a necking,
this was achieved by employing a video-controlled tensile testing machine. Recovery properties of the
sample were studied in step-cycle runs, where the load was applied stepwise and interrupted after each
step by an unloading−reloading loop. Simultaneous with the mechanical testing, the related texture
changes were determined by a measurement of the WAXS patterns. In spite of the large changes in the
gross mechanical properties from solid- to rubberlike, there exists a common general scheme for the
deformation behavior. For all samples, one finds four characteristic points where the differential
compliance changes. They may be associated with (1) the onset of isolated slip processes, (2) a change
into a collective activity of the slips, (3) the beginning of crystallite fragmentation, and (4) chain
disentanglement resulting in a finite truly irreversible deformation. When the crystallinity is increased,
the stresses at the four transition points also increase. The related strains, however, remain essentially
constant. Crystal textures are also a function of the imposed strain only, the dependencies being common
for all samples. Experiments support the novel picture of a granular substructure of the crystalline lamellae
as a basic structural feature. Block slips with the three surfaces as slip planes enable the system to
easily react on each imposed strain in a well-defined way.
The thermal behavior of several electrically conducting solids under high incident electron fluence in high vacuum was evaluated. At electron energies of up to ∼200 keV, the depth-dose relationship for electron penetration into the materials was considered, and the resulting energy deposition profile from the surface was revealed to extend to a maximum of ∼175 µm below the surface depending on the anode material. Black body radiation is considered as the major mechanism that balances the power deposited in the material on the timescales of interest. Comparing the radiated power density at the sublimation temperature for different materials, metallic/nonmetallic, revealed that pyrolytic graphite anodes may radiate over 20 times more power than metallic anodes before failure due to sublimation. In addition, transparent pyrolytic graphite anodes (with a thickness on the order of several tens of micrometer) potentially radiate up to 40 times that of metallic anodes, since heating by the electron beam is approximately uniform throughout the thickness of the material, thus radiation is emitted from both sides. Experimental results obtained from titanium and pyrolytic graphite anodes validate the thermal analysis.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.