The combustion process of pyrotechnics was studied in order to obtain informations of the rate control parameters of burning rate. The pyrotechnics tested was made of Mg (magnesium) and TF (polyfluoroethylene). The burning rate measurements revealed that the burning rate of the Mg/TF propellants (pellet in shape) increases with increasing the weight fraction (ξ) of Mg in the range of ξ > 0.33. Though the adiabatic flame temperature is the maximum at ξ = 0.33, the burning rate increases with decreasing the flame temperature. The total burning surface area of the Mg particles mixed with in the unit mass of propellant plays an important role on the oxidation process in the gas phase just above the propellant burning surface. The heat flux feedback from the gas phase to the propellant burning surface increases with increasing ξ. Therefore, the burning rate increases as ξ increases.
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