The continuing hydration of unhydrated cement grains was proven to be one of the most important processes for promoting the self-healing effect within cementitious composites, by generating the CSH gels as valuable healing products, not only sealing the microcracks but also being able to provide some mechanical recovery of the material, as well [1]. It was also concluded that the process slows down in time, being strongly connected to concrete age. In order to ensure the continuous hydration potential for the cementitious materials, also as essential self-healing (SH) promoter, the addition of reactive grains is considered. This paper presents preliminary aspects regarding the possibility of polymeric encapsulation of some reactive grains and the feasibility of the concept in terms of matrix compatibility to the addition and also their SH performance under induced, controlled cracking. The considered self-healing addition behaves intelligent as it would react with water only when the cracking occurs, creating gaps in the waterproofing coating. The object of this research is less focused on regaining the mechanical characteristics of concrete, like pre-cracking strength, but mainly on preventing aggressive agents from entering in the concrete mass and aggressing the reinforcement.
Leather and wool waste represent a high concern due to the low level of valorization and circular economy demands for upcycling of biomass resources. Both biomasses can be easily processed as protein hydrolysates and used as functional additives due to the amphiphilic and tunable properties of collagen and keratin proteins. The chemical, physical, and structural investigations of collagen and keratin hydrolysate properties showed that the chelating abilities due to carboxylic groups can be exploited for gypsum retardant additives. The molecular weights and amino acid compositions of three different hydrolysates showed only slight influences on the setting time of gypsum; all three proteins delayed the setting time of gypsum between 60 and 120 min, as compared to the commercial plaster with a 30 min setting time. Higher molecular weight and more carboxylic active groups showed slight improvements in the setting time of mortars. The improved properties of keratin hydrolysate as compared to low molecular collagen hydrolysate were attributed to foaming and conductive properties. The mechanism of mortar setting delaying through calcium ions complexation by protein hydrolysates was shown by electric conductivity evolution of plasters with and without protein additives over time, supported by foaming properties, amino acid, and functional groups’ composition. Lower bending strength values for the higher concentration of proteins do not reduce the potential to use the protein hydrolysates as retardant additives in mortar fabrication.
The paper follows the potential practice of fiber reinforced concrete (FRC) as a solution for airport`s runway pavements, in order to increase the bearing strength, resulting in decreasing the height of the concrete layer that is currently used. Experimentally, the study focuses on the properties of fiber reinforced Portland cement concrete using 3 different percentages (0.5%, 1% and 1.5% of the concrete volume) and 4 different types of fiber (for 1% percentage – hooked steel fiber 50 mm length, hooked steel fiber 30 mm length, crimped steel fiber 30 mm length and polypropylene fiber 50 mm lenght), using as reference a plain concrete with 5 MPa flexural strength. More exactly, the study presents the change in compressive and flexural strength, shrinkage, thermal expansion factor, elastic modulus and Poisson`s ratio over fiber type and dosage. For the highest performance concrete (7 MPa flexural strength), it has been made a study using two methods for rigid airport pavements design (general method and optimized method), and one method for evaluation of bearing strength (ACN – PCN method), which is compared to a plain 5 MPa concrete. Furthermore, the decrease in the slab`s thickness proportionally to the growth of the flexural strength is emphasized by evaluating the slab`s height for a high performance 9 MPa concrete using both design methods.
This paper proposes a methodology to assess the rheological behavior of cement paste as a first step to linking this behavior to the robustness of the Self Compacting Mortar (SCM) and further extending this to Self-Compacting Concrete (SCC). Cement paste�s rheological behavior was assessed in terms of spread (using a mini-cone) and time of flow (using the Marsh cone). The results show that the type of superplasticizer (SP) admixture has a great influence on the rheological behavior of cement paste and for each combination of binder and superplasticizer admixture there is a specific range of water to binder ratio in which the rheology of paste seems to be appropriate for obtaining a robust SCC mix. The influence of SP and limestone filler addition on the kinetic of cement hydration process was assessed by X Ray Diffraction and thermal analysis (TG-DTA). Based on these results, i.e. an important delaying effect exerted by superplasticizer additions on cement hydration process at early ages (1 day), it can be concluded that when designing SCC for the precast industry - where the early strength of concrete is of high importance, analyzing the early strength of binder paste together with the robustness properties is very important. The correlation between the two aspects - rheology and early strength -is very important in this case in order to obtain applicable results in practice.
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