Converting toxic Cr(vi) to benign Cr(iii) would offer a solution to decontaminate drinking water.

Electrochemical methods using carbon electrodes are an attractive option for the detection and reduction of toxic Cr(vi) to benign Cr(iii) in drinking water.

The nature of the buffer influences the PCET step gating Cr(vi) reduction in water at pH 4.75, as well as the extent of deposition on carbon electrodes. Electrode activity is recovered without polishing, through a simple acid wash step.

New lithium electrolytes compatible with high energy density cells are critical for lithium metal battery applications, but dendrite formation associated with the use of dilute organic electrolytes complicates their realization. High-concentration electrolytes mitigate some of the issues of the electrolytes but introduce additional problems, such as low conductivity and high cost. Hence, pseudo-concentrated electrolytes, wherein a co-solvent is added to a dilute electrolyte, have been presented as a possible alternative to both dilute and concentrated electrolytes. However, the effect that the co-solvent has on the electrolyte properties at both macroscopic and microscopic levels is unknown. Here, a study of the structure and electrochemical properties of two electrolytes as a function of co-solvent concentration is presented using an array of spectroscopies (FTIR, ATR–FTIR, and nuclear magnetic resonance) and computational methods (density functional theory calculations). The chosen electrolytes comprised two different lithium salts (LiPF 6 and LiTFSI) in a mixture of dimethyl carbonate (DMC) with 1,1,1,3,3-pentafluorobutane (PFB) as the co-solvent. Our results show that in the case of the LiPF 6 /DMC electrolyte, the addition of a co-solvent (PFB) with a larger dielectric constant results in the strengthening of the lithium–anion interaction and the formation of aggregate species since PFB does not interact with the anion. Conversely, in the LiTFSI/DMC electrolyte, the co-solvent appears to interact with the anion via hydrogen bonds, which leads to the dissociation of contact ion pairs. The change in ionic speciation of the electrolytes upon addition of PFB provides a reasonable framework to explain the different trends in both the bulk and interfacial macroscopic properties, such as conductivity, viscosity, and electrochemical stability. Overall, our findings demonstrate that the interactions between the anion and the co-solvent must be taken into consideration when adding a co-solvent because they play a major role in determining the final electrolyte properties.

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