Highly efficient green and orange-red PhOLEDs with low efficiency roll-off enabled by a bipolar violet-blue phenanthroimidazole-based fluorophore.

A self-priming centrifugal pump can be used in various areas such as agricultural irrigation, urban greening, and building water-supply. In order to simulate the gas-water two-phase flow in the self-priming process of a self-priming centrifugal pump, the unsteady numerical calculation of a typical self-priming centrifugal pump was performed using the ANSYS Computational Fluid X (ANSYS CFX) software. It was found that the whole self-priming process of a self-priming pump can be divided into three stages: the initial self-priming stage, the middle self-priming stage, and the final self-priming stage. Moreover, the self-priming time of the initial and final self-priming stages accounts for a small percentage of the whole self-priming process, while the middle self-priming stage is the main stage in the self-priming process and further determines the length of the self-priming time.

Donor-acceptor (D-A) molecular architecture has been shown to be an effective strategy for obtaining high-performance electroluminescent materials. In this work, two D-A molecules, Ph-BPA-BPI and Py-BPA-BPI, have been synthesized by attaching highly fluorescent phenanthrene or pyrene groups to the C6- and C9-positions of a locally excited-state emitting phenylamine-phenanthroimidazole moiety. Equipped with good physical and hybridized local and charge-transfer properties, both molecules show high performances as blue emitters in nondoped organic light-emitting devices (OLEDs). An OLED using Ph-BPA-BPI as the emitting layer exhibits deep-blue emission with CIE coordinates of (0.15, 0.08), and a maximum external quantum efficiency (EQE), current efficiency (CE), and power efficiency (PE) of 4.56 %, 3.60 cd A(-1) , and 3.66 lm W(-1) , respectively. On the other hand, a Py-BPA-BPI-based, sky-blue OLED delivers the best results among nondoped OLEDs with CIEy values of < 0.3 reported so far, for which a very low turn-on voltage of 2.15 V, CIE coordinates of (0.17, 0.29), and maximum CE, PE, and EQE values of 10.9 cd A(-1) , 10.5 lm W(-1) , and 5.64 %, were achieved, respectively. More importantly, both devices show little or even no efficiency roll-off and high singlet exciton-utilizing efficiencies of 36.2 % for Ph-BPA-BPI and 39.2 % for Py-BPA-BPI.

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