Natural photosynthetic photonic nanostructures can show sophisticated light-matter interactions including enhanced light absorption by slow light even for highly pigmented systems. Beyond fundamental biology aspects, these natural nanostructures are very attractive as blueprints for advanced photonic devices. But the soft-matter biomimetic implementations of such nanostructures is challenging due to the low refractive index contrast of most organic photonic structures. Excitonic organic materials with near-zero index (NZI) optical properties allow overcoming these bottlenecks. Here, it is demonstrated that the combination of NZI thin films with photonic multilayers like the ones found in nature enables broadband tunable strong reflectance as well as slow light absorption enhancement and tailored photoluminescence properties in the full VIS spectrum. Moreover, it is shown that this complex optical response is tunable, paving the way toward the development of active devices based on all-polymer and near-zero index materials photonic structures.
Optical Tamm states (OTS) are confined optical modes that can occur at the interface between two highly reflective structures. However, due to the strong reflectance required, their implementation with highly processable and metal-free flexible materials has proven challenging. Herein, we develop the first structure supporting OTS based only on organic polymeric materials, demonstrating a photonic platform based on non-critical, widely available and easily processable materials. The structures fabricated present large areas and consist of a narrowband multi-layered polymeric distributed Bragg reflector (DBR) followed by a thin film of J-aggregate molecular excitonic material that can act as a highly reflective surface within a narrowband range. We take advantage of the narrowband spectral response of the DBR and of the reflective molecular layer to tune the OTS band by varying the periodicity of the multilayer, opening the door for the fabrication of OTS structures based on lightweight integrable excitonic devices with cost-effective procedures.
Light-harvesting complexes in natural photosynthetic systems, such as those in purple bacteria, consist of photo-reactive chromophores embedded in densely packed “antenna” systems organized in well-defined nanostructures. In the case of purple bacteria, the chromophore antennas are composed of natural J-aggregates such as bacteriochlorophylls and carotenoids. Inspired by the molecular composition of such biological systems, we create a library of organic materials composed of densely packed J-aggregates in a polymeric matrix, in which the matrix mimics the optical role of a protein scaffold. This library of organic materials shows polaritonic properties which can be tuned from the visible to the infrared by choice of the model molecule. Inspired by the molecular architecture of the light-harvesting complexes of Rhodospirillum molischianum bacteria, we study the light–matter interactions of J-aggregate-based nanorings with similar dimensions to the analogous natural nanoscale architectures. Electromagnetic simulations show that these nanorings of J-aggregates can act as resonators, with subwavelength confinement of light while concentrating the electric field in specific regions. These results open the door to bio-inspired building blocks for metamaterials from visible to infrared in an all-organic platform, while offering a new perspective on light–matter interactions at the nanoscale in densely packed organic matter in biological organisms including photosynthetic organelles.
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