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In this work, four bench-scale plants containing soil spiked with four herbicides (2,4-Dichlorophenoxyacetic acid (2,4-D), oxyfluorfen, chlorsulfuron and atrazine) undergo treatment consisting of an electrokinetic soil flushing (EKSF). Results clearly demonstrate that efficiency of EKSF depends on the chemical characteristic of the pesticide used. The amount of pesticide collected in the anode well is more significant than that collected in the cathode wells, indicating that the electromigration is much more important than drainage by electro-osmotic flux for this application. After 15 d of treatment, the 2,4-D is the pesticide most efficiently removed (95% of removal), while chlorsulfuron is the pesticide more resilient to the treatment. Additionally, volatilization was found to be a process of the major significance in the application of electrokinetic techniques to soil polluted with herbicides and because of that it should always be taken into account in the future design of full-scale processes.

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The purpose of this study was to develop an inexpensive, simple, and highly selective cork-modified carbon paste electrode for the determination of Pb(II) by differential pulse anodic stripping voltammetry (DPASV) and square-wave anodic stripping voltammetry (SWASV). Among the cork–graphite electrodes investigated, the one containing 70% w/w carbon showed the highest sensitivity for the determination of Pb(II) in aqueous solutions. Under SWASV conditions, its linear range and relative standard deviation are equal to 1–25 µM and 1.4%, respectively; the limit of detection complies with the value recommended by the World Health Organization. To optimize the operating conditions, the selectivity and accuracy of the analysis were further investigated by SWASV in acidic media. Finally, the electrode was successfully applied for the determination of Pb(II) in natural water samples, proving to be a sensitive electrochemical sensor that meets the stringent environmental control requirements.