The generality of the palladium-catalyzed C−C coupling Negishi reaction when applied to haloBODIPYs is demonstrated on the basis of selected starting BODIPYs, including polyhalogenated and/or asymmetrical systems, and organozinc reagents. This reaction is an interesting synthetic tool in BODIPY chemistry, mainly because it allows a valuable regioselective postfunctionalization of BODIPY chromophores with different functional groups. In this way, functional patterns that are difficult to obtain by other procedures (e.g., asymmetrically functionalized BODIPYs involving halogenated positions) can now be made. The regioselectivity is achieved by controlling the reaction conditions and is based on almost-general reactivity preferences, and the nature of the involved halogens and their positions. This ability is exemplified by the preparation of a series of new BODIPY dyes with unprecedented substitution patterns allowing noticeable lasing properties.

The shadow effect caused by nearby objects or the lack of cleaning significantly affects the performance of photovoltaics (PV) installations. This article analyses the bypass diode electrical behaviour and the thermal response of a PV crystalline module under shading or soiling conditions. PV cells of different substrings were covered progressively to simulate the effect of shading or soiling while a programmable electronic DC load was connected to a PV module to set an operating voltage. Three different tests were made to different PV crystalline technology. The paper characterizes in real conditions the I–V curve, bypass diode current, and front and back side PV cell temperature with contact sensor and infrared (IR) thermography, respectively. The results showed that the operation voltage established in the PV module defines the electrical bypass diode current and thermal response under normal operating conditions, shading or soiling. To show the bypass diode behaviour in such conditions, I–V curves were obtained, pointing out the value of the current that flows through bypass diodes in the whole voltage range.

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Aerial infrared (IR) thermography has been implemented in recent years, proving to be a powerful and versatile technique for performing maintenance at photovoltaic (PV) plants. Its application speed and reliability using unmanned aerial vehicles (UAVs) or drones make it extremely interesting at large PV plants, due to the associated savings in time and costs. Ground-level thermographic inspection is slower and more costly to apply, although it does provide higher optical resolution, due to being conducted closer to the PV modules being inspected. Both techniques used in combination can improve the diagnosis. An IR thermography inspection strategy is proposed for PV plants based on two stages. The first stage of the inspection is aerial, enabling thermal faults to be detected and located quickly and reliably. The second stage of the inspection is done on the ground and applied only to the most relevant incidents revealed in the first stage. This inspection strategy was applied to a 100 kW PV plant, with an improved diagnosis verified via this procedure, as the ground-level inspection detects one-off thermal incidents from objects creating shade and from solar reflections. For PV modules with open circuits or open substrings, the use of one technique or another is immaterial.