Scanning tunneling microscopy (STM) is used to study the dissociation of molecular oxygen on Ag(100) induced by inelastic electron tunneling (IET) at 5 K. This dissociation is possible above 3.3 V with a yield of (3.63 ± 0.47) × 10(-9) per electron. Dissociation leads to three different types of hot atom motion: lateral motion, a cannon ball mechanism, and abstractive dissociation. Analysis of the I-t characteristics during dissociation suggests that the dissociation is proceeded by an adsorption site change.

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We investigate the induced growth of a Ag layer on a Cu(111) surface by variable low-temperature scanning tunneling microscopy between 100 and 140 K at submonolayer coverage. Without any interference by the scanning process, the Ag atoms form a two-dimensional gas on the Cu(111) surface. Imaging the surface at elevated voltage induces nucleation and growth of one-dimensional Ag stripes of monolayer height, eventually filling the surface of the imaged area completely. The stripes consist of rods of atoms with a preferential length of (1.88 ± 0.10) nm, corresponding to approx. seven or eight Ag atoms on eight to nine Cu hollow sites. At a ratio of approximately 1:3, rods of double length are the second most observed species. The rods stack in the ⟨112⟩ directions at the √3 distance of Cu(111). Although all equivalent three surface directions are observed, their abundance is not equally distributed, such that the rod direction aligned with the fast scanning direction predominates. At slow growth rates, it is possible to create a striped pattern with one surface direction only.

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If a material grows on another material with a largely different lattice constant, which of the two adapts for an energetically favorable growth? To tackle this question, we investigate the growth of Ag on Cu(111) by variable temperature scanning tunneling microscopy. The structures grown between 120 and 170 K are remarkably different from those grown between 200 and 340 K. The low-temperature structure is rectangular-like and consists of stacked rods, 7 to 8 Ag atoms long, which form a superstructure without long-range order. This structure covers the whole surface prior to nucleation of further layers. The high-temperature structure is hexagonal and consists of misfit dislocations forming 8 × 8 to 10 × 10 superstructures. For this structure, second layer nucleation sets in far before the closure of the first monolayer. While both structures are driven by the large lattice misfit between the two materials, the growing Ag layer adapts to the Cu surface at low temperature, while the Cu surface adapts to the growing Ag layer at higher temperature.