Mn-Co-based catalysts were loaded to ceramic filters element by impregnation for the coprocessing of dust and nitrogen oxide (NOx) in flue gas. The influence of the Mn/Co ratio and loading on the catalytic performance was investigated. The Mn-Co-based catalytic ceramic filter with a Mn/Co molar ratio of 2/1 can achieve 99% NO conversion by selective catalytic reduction of NOx with NH3 (NH3-SCR) in the temperature range of 100−180 °C, but its resistance to H2O was relatively poor. The filter element was modified by PTFE to improve the H2O resistance. After modification, the catalytic ceramic filter showed superior resistance to H2O and SO2 at low temperatures (100–180 °C) and satisfactory self-cleaning performance.
The catalyst particles were removed from fluid catalytic cracking (FCC) slurry oil by two-step separation processing. FCC slurry oil was mixed with water and surfactant to make the lower viscosity emulsion. The catalyst particles were removed from the emulsion using the modified hydrophobic ceramic membrane (0.1μm) and then the water was filtered out from oil/water emulsion using an unmodified hydrophilic ceramic membrane (0.05μm) at room temperature. The separation efficiency of catalyst particles and emulsion reached 99.9% and the oil/water separation efficiency also reached 99.9%. FCC slurry oil was effectively purified at room temperature by a two-step treatment.
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