A superhydrophobic and superoleophilic
copper mesh with excellent
oil–water separation efficiency was successfully fabricated
via electrodeposition and then surface modification with lauric acid.
The surface morphologies, chemical composition, and wettability were
characterized by means of scanning electron microscopy (SEM), atomic
force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), Fourier
transform infrared (FT-IR) spectroscopy, and water contact angle (WCA)
measurements. It was found that the as-prepared surface is both superhydrophobic
and superoleophilic, with static WCA values as high as 155.5°
± 3° and an oil contact angle (OCA) of 0°. Furthermore,
the as-prepared surface exhibited excellent oil–water separation
efficiency including petroleum, toluene, hexane, gasoline and diesel,
even after being recycled 10 times. In addition, the as-prepared copper
mesh shows self-cleaning character with water and chemical stability.
This study provides a facile, inexpensive, and environmentally friendly
route to fabricate large-scale and excellent oil–water separation
surface with high separation efficiency for a great number of potential
applications.
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