In the present paper, investigations of CdSe loaded poly(diallyl dimethyl ammonium chloride) (PDADMAC) nanocomposites and pure PDADMAC synthesized by wet chemical technique have been carried out. Fourier transform infrared and X-ray diffraction analysis have been performed to reveal the structural details of pure polymer and polymer nanocomposite (PNC). The dielectric behavior of pure polymer and PNC has been recorded, which results in higher value of the real and imaginary part of dielectric constant for PNC, as compared with pure PDADMAC. The increase is attributed to the addition of CdSe quantum dots to the pure polymer. The contribution of ionic and electronic polarization has been observed at higher frequency. The theoretical fitting of Cole-Cole function to the experimental data of dielectric constant of PNC and pure PDADMAC results in the determination of relaxation time and conductivity of space charge carriers. The CdSe loaded polymer nanocomposite has been used as an electrolyte in the battery fabrication with configuration Al/PNC/Ag2O. The ac conductivity measurements have been carried out for both samples in a frequency window of 1 kHz–5 MHz and at different temperatures varying from 298 K to 523 K. Activation energy (Ea) has been determined for pure polymer as well as PNC and is found to be less for PNC, as compared with pure polymer. Further, impedance measurement at different temperatures results in two frequency ranges corresponding to ionic conduction and blocking electrode effect. The value of bulk resistance for pure polymer and PNC has been found to be 3660 Ω and 442 Ω, respectively, at 298 K temperature. Electric modulus has been determined and is observed to support the dielectric constant data; it further reveals the deviation from Debye behavior at a higher frequency.

The important enhancement in the structural, dielectric and optical properties of pure polymer and CdSe incorporated polyvinyl pyrrolidone has been reported in this paper. The surface morphology of CdSe/PVP nanocomposite film is studied by using scanning electron microscopy (SEM). The chemical composition of different elements has been reported using energy dispersive X-ray (EDX) spectrum. The structure of polymer nanocomposite is determined with the help of X-ray diffraction (XRD) spectrum and is observed to be hexagonal. Particle size, intercrystalline separation, interplanner spacing, lattice parameters, strain and dislocation factors are calculated using XRD results. Fourier transform infrared spectroscopy (FTIR) and Photoluminescence (PL) analysis have been studied in order to check the possible interaction between CdSe quantum dots and polyvinyl pyrrolidone (PVP) matrix. The ac conductivity of CdSe/PVP nanocomposite is found to be higher as compared to pure polymers. The highest value of conductivity observed at 60203 Hz and at 523 K is found to be [Formula: see text][Formula: see text]Sm[Formula: see text]. Comparative study of dielectric constant, dielectric losses, dissipation factor, electric modulus and impedance has been performed. The semi-circles in impedance measurement for both materials show the bulk electrical properties that result in single relaxation process in CdSe/PVP nanocomposite.

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