No abstract

Chlorophylls are important antioxidants found in foods. We explored the mechanisms through which the a and b forms of chlorophyll and of pheophytin (the Mg-chelated form of chlorophyll) reduce oxidation: we used comet assay to measure prevention of H 2 O 2 DNA damage; we tested for quenching of 1,1-diphenyl-2-picrylhydrazyl (DPPH); we measured the ability to chelate Fe(II); and, we tested their ability to prevent formation of thiobarbituric acid reactive substances (TBARS) during Cu-mediated peroxidation of low density lipoprotein (LDL) in a chemical assay. All chlorophylls and pheophytins showed significant dose-dependent activity in the assays, with the pheophytins being the strongest antioxidants. Thus, these chemicals can prevent oxidative DNA damage and lipid peroxidation both by reducing reactive oxygen species, such as DPPH, and by chelation of metal ions, such as Fe(II), which can form reactive oxygen species.

The objectives of this study were to identify the antioxidants and antioxidant axtivity in 27 of Taiwan’s indigenous vegetables. Lycium chinense (Lc), Lactuca indica (Li), and Perilla ocymoides (Po) contained abundant quercetin (Que), while Artemisia lactiflora (Al) and Gynura bicolor (Gb) were rich in morin and kaempferol, respectively. Additionally, Nymphoides cristata (Nc) and Sechium edule (Se)-yellow had significantly higher levels of myricetin (Myr) than other tested samples. Cyanidin (Cyan) and malvidin (Mal) were abundant in Gb, Abelmoschus esculentus Moench (Abe), Po, Anisogonium esculentum (Retz.) Presl (Ane), Ipomoea batatas (Ib)-purple, and Hemerocallis fulva (Hf)-bright orange. Relatively high levels of Trolox equivalent antioxidant capacity (TEAC), oxygen radical absorption capacity (ORAC), and 1,1-diphenyl-2-picryl-hydrazyl (DPPH) radical scavenger were generated from extracts of Toona sinensis (Ts) and Po. Significant and positive correlations between antioxidant activity and polyphenols, anthocyanidins, Que, Myr, and morin were observed, indicating that these phytochemicals were some of the main components responsible for the antioxidant activity of tested plants. The much higher antioxidant activity of Po, Ts, and Ib (purple leaf) may be related to their higher Cyan, Que, and polyphenol content.

The “Santa Ana” wind is an offshore flow that affects Southern California periodically during the winter half of the year, typically between September and May. The winds can be locally gusty, particularly in the complex terrain of San Diego County, where the winds have characteristics of downslope windstorms. These winds can cause and/or rapidly spread wildfires, the threat of which is particularly acute during the autumn season before the onset of winter rains. San Diego’s largest fires, including the Cedar fire of 2003 and Witch Creek fire of 2007, occurred during Santa Ana wind events. A case study of downslope flow during a moderately intense Santa Ana event during mid-February 2013 is presented. Motivated by the need to forecast winds impinging on electrical lines, the authors make use of an exceptionally dense network of near-surface observations in San Diego County to calibrate and verify simulations made utilizing the Advanced Research version of the Weather Research and Forecasting (WRF) Model, which in turn is employed to augment the observations. Results demonstrate that this particular Santa Ana episode consists of two pulses separated by a protracted lull. During the first pulse, the downslope flow is characterized by a prominent hydraulic jumplike feature, while during the second one the flow possesses a clear temporal progression of winds downslope. WRF has skill in capturing the evolution and magnitude of the event at most locations, although most model configurations overpredict the observed sustained wind and the forecast bias is itself biased.

The authors survey a series of modeling studies that have examined the influences that cloud microphysical processes can have on tropical cyclone (TC) motion, the strength and breadth of the wind field, inner-core diabatic heating asymmetries, outer-core convective activity, and the characteristics of the TC anvil cloud. These characteristics are sensitive to the microphysical parameterization (MP) in large part owing to the cloud-radiative forcing (CRF), the interaction of hydrometeors with radiation. The most influential component of CRF is that due to absorption and emission of longwave radiation in the anvil, which via gentle lifting directly encourages the more extensive convective activity that then leads to a radial expansion of the TC wind field. On a curved Earth, the magnitude of the outer winds helps determine the speed and direction of TC motion via the beta drift. CRF also influences TC motion by determining how convective asymmetries develop in the TC inner core. Further improvements in TC forecasting may require improved understanding and representation of cloud-radiative processes in operational models, and more comprehensive comparisons with observations are clearly needed.