Although there have been intense efforts to fabricate large three-dimensional photonic crystals in order to realize their full potential, the technologies developed so far are still beset with various material processing and cost issues. Conventional top-down fabrications are costly and time-consuming, whereas natural self-assembly and bottom-up fabrications often result in high defect density and limited dimensions. Here we report the fabrication of extraordinarily large monocrystalline photonic crystals by controlling the self-assembly processes which occur in unique phases of liquid crystals that exhibit three-dimensional photonic-crystalline properties called liquid-crystal blue phases. In particular, we have developed a gradient-temperature technique that enables three-dimensional photonic crystals to grow to lateral dimensions of ~1 cm (~30,000 of unit cells) and thickness of ~100 μm (~ 300 unit cells). These giant single crystals exhibit extraordinarily sharp photonic bandgaps with high reflectivity, long-range periodicity in all dimensions and well-defined lattice orientation.

We demonstrate in this paper an electrically tunable photonic device based on one-dimensional photonic crystal (PC) infiltrated with polymer-stabilized cholesteric texture (PSCT) as a central defect layer. With the hybrid PC/PSCT structure, not only is the wavelength of each defect mode switchable among three major stable states by various appropriate frequency-modulated voltage pulses, but also the intensity can be electrically tuned in multi-metastable states. As a result, an electrically controllable multichannel photonic device with several alluring features is proposed. It is wavelength-switchable, intensity-tunable, and polarizer-free and possesses optical tristability in the defect modes to reduce power consumption.

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The ionic effect in nematic liquid-crystal (LC) cells containing the azo dye methyl red was investigated by means of dielectric spectroscopy, measurements of voltage holding ratio (VHR) and ultraviolet/visible absorption spectroscopy. The experimental results indicated that incorporating a minute amount of the methyl red (< 0.03 wt%) in the LC host leads to the suppression of the ionic effect caused by impurity ions. Practically, the doped LC cells with a dye content of 0.02 wt% showed improved VHR and promoted lifetime by 15% and 180%, respectively, in virtually no expense of the optical transmittance.

Controlling light flow in the directed-assembly of blue-phase liquid crystal (BPLC) microspheres with curvature boundaries and random domain of cubic lattices is a highly interesting photonic phenomenon. A strategy of efficient random lasing with resonant feedback based on a microemulsion comprising of BPLC, laser dye and block copolymer is presented here. BPLCs are produced with a microfluidic apparatus and confined in microspheres. These spatially-assembled dye-doped BPLC microdroplets are used as a source for the generation of laser light. Recurrent light flow inside the droplets comprising of face-centered cubic blue-phase boundaries provides omnidirectional lasing with efficient coherent feedback which is not supported by conventional resonators. The topologically directed assemblies of BPLC microspheres with explicit shape and symmetry are essential for reducing threshold and increasing Q-factor of laser emission. These results provide new avenues for a wide range of photonic applications.