Topological materials have become the focus of intense research in recent years, since they exhibit fundamentally new physical phenomena with potential applications for novel devices and quantum information technology. One of the hallmarks of topological materials is the existence of protected gapless surface states, which arise due to a nontrivial topology of the bulk wave functions. This review provides a pedagogical introduction into the field of topological quantum matter with an emphasis on classification schemes. We consider both fully gapped and gapless topological materials and their classification in terms of nonspatial symmetries, such as time-reversal, as well as spatial symmetries, such as reflection. Furthermore, we survey the classification of gapless modes localized on topological defects. The classification of these systems is discussed by use of homotopy groups, Clifford algebras, K-theory, and non-linear sigma models describing the Anderson (de-)localization at the surface or inside a defect of the material. Theoretical model systems and their topological invariants are reviewed together with recent experimental results in order to provide a unified and comprehensive perspective of the field. While the bulk of this article is concerned with the topological properties of noninteracting or mean-field Hamiltonians, we also provide a brief overview of recent results and open questions concerning the topological classifications of interacting systems.

We discuss a topological classification of insulators and superconductors in the presence of both (nonspatial) discrete symmetries in the Altland-Zirnbauer classification and spatial reflection symmetry in any spatial dimensions. By using the structure of bulk Dirac Hamiltonians of minimal matrix dimensions and explicit constructions of topological invariants, we provide the complete classification, which still has the same dimensional periodicities with the original Altland-Zirnbauer classification. The classification of reflectionsymmetry-protected topological insulators and superconductors depends crucially on the way reflection symmetry operation is realized. When a boundary is introduced, which is reflected into itself, these nontrivial topological insulators and superconductors support gapless modes localized at the boundary.

Topological semimetals can support one-dimensional Fermi lines or zero-dimensional Weyl points in momentum space, where the valence and conduction bands touch. While the degeneracy points in Weyl semimetals are robust against any perturbation that preserves translational symmetry, nodal lines require protection by additional crystalline symmetries such as mirror reflection. Here we report, based on a systematic theoretical study and a detailed experimental characterization, the existence of topological nodal-line states in the non-centrosymmetric compound PbTaSe2 with strong spin-orbit coupling. Remarkably, the spin-orbit nodal lines in PbTaSe2 are not only protected by the reflection symmetry but also characterized by an integer topological invariant. Our detailed angle-resolved photoemission measurements, first-principles simulations and theoretical topological analysis illustrate the physical mechanism underlying the formation of the topological nodal-line states and associated surface states for the first time, thus paving the way towards exploring the exotic properties of the topological nodal-line fermions in condensed matter systems.