The over-exploitation of fossil fuels means that research into alternative sustainable energy sources is crucial for the scientific community. The harvesting of solar energy via photocatalysis is a key approach to developing these alternatives. Furthermore, photocatalytic materials show great promise for degradation of pollutants. However, limitations in incident light utilization and charge separation are major drawbacks that restrict the activity of current artificial photosystems. Construction of hollow nano-sized photocatalysts is emerging as a promising approach to fabricating novel and effective materials, as hollow photocatalysts possess unique properties that may be exploited to overcome these challenges. This review gives a concise overview of the advantages of hollow structures for this purpose, the methodology used to prepare hollow photocatalysts, and the current state-of-the-art in the development of hollow structure photocatalysts for energy production and environmental applications.

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Low dimensional transition metal carbide and nitride (MXenes) have been emerging as frontier materials for energy storage and conversion. Ti3C2Tx was the first MXenes that discovered and soon become the most widely investigated among the MXenes family. Interestingly, Ti3C2Tx exhibits ultrahigh catalytic activity towards the hydrogen evolution reaction. In addition, Ti3C2Tx is electronically conductive, and its optical bandgap is tunable in the visible region, making it become one of the most promising candidates for the photocatalytic hydrogen evolution reaction (HER). In this review, we provide comprehensive strategies for the utilization of Ti3C2Tx as a catalyst for improving solar-driven HER, including surface functional groups engineering, structural modification, and cocatalyst coupling. In addition, the reaming obstacle for using these materials in a practical system is evaluated. Finally, the direction for the future development of these materials featuring high photocatalytic activity toward HER is discussed.