This work aims to modify the copper ferrite with a porphyrin derivatives by a simple method of self-assembly. The resultant porphyrin-modified copper ferrite was utilized as a photocatalyst for the removal of methyl blue dyes (MB) from aqueous solution. The results showed that the porphyrin nanofibers were well-intergrated with the copper ferrite nanoparticles. The porphyrin-modified copper ferrite materials exhibited the high photocatalytic performance toward MB dye with the removal percentage of approximately 100% after 200 minutes of irradiation under simulated light. The catalyst could be facilely separate by using a external magnet and reused.
This paper describes a novel process for the synthesis of TiO2 from titanium slag, which is realized via roasting titanium slag with KHSO4, acid leaching and hydrolysis. The results showed that the optimum conditions were a mass ratio of KHSO4 to titanium slag of 6, a temperature of 600 oC for 1,5 hours. Besides, this study investigated the possibility of synthesized TiO2 for photocatalytic degradation of methylene blue.
CuxMg1.xFe2O4 nanoparticles were successfully synthesized by co-precipitation. The samples were calcined at 900 oC for 3 h and X-ray diffraction analysis showed that Cu0.5Mg0.5Fe2O4 had a single phase cubic spinel structure, while formation of secondary phase of Fe2O3 was observed in XRD patterns of CuFe2O4, MgFe2O4. The saturation magnetization (Ms) of Cu0.5Mg0.5Fe2O4 is in between the saturation magnetization values of CuFe2O4 and MgFe2O4 nanoparticles, CuFe2O4 is a ferromagnetic material, while MgFe2O4 and Cu0.5Mg0.5Fe2O4 show superparamagnetic behavior. The synthesized spinel ferrites were fully characterized using scanning electron microscopy (SEM), FTIR spectroscopy, energy dispersive spectroscopy (EDS) and UV-vis spectrophotometry.
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