In the present study magneto-polymer composite coatings are fabricated using nano Zn ferrite, Mn ferrite, Ni ferrite, Zn-Mn ferrite and Zn-Ni ferrite by spraying method. The complex permeabilities, Complex permittivities and microwave absorbing properties within the low frequency of these composites were characterized and investigated. The results showed that the magnetism of the mixed spinel ferrites ( Mn ferrite, Zn-Ni ferrite, Zn-Mn ferrite) are strong but the dielectric properties are weaker, while the magnetism of the normal spinel ferrites (Zn ferrite) is the weakest but provide with a big storage capability of electric energy. The absorbing characteristics of the spinel ferrites are better at 300 kHz-1.5GHz, with minimum absorption of 12.5 dB and the maximum absorption at 480MHz, 1050 MHz and 1400 MHz. The microwave absorbing property of the mixed spinel ferrite Zn-Mn ferrite is best having the RL value being -42.5 dB at 1400GHz.
Electromagnetic microwave absorbing composite material containing magnetic Mn-Zn ferrite/conductive polyaniline nanocomposites introducing into epoxy resin were fabricated. The conductivity of the Mn-Zn ferrite/polyaniline nanocomposites were investigated by a four point probe method. Complex permeability and reflection loss of the Mn-Zn ferrite/conductive polyaniline/epoxy resin composites have been studied in the frequency of 30 MHz to 1 GHz. It has been found that the conductivity of the nanocomposites can be tailored by controlling the weight percentage of polyaniline. The complex permeability increased with the decreasing weight percent of polyaniline. The composite with the polyaniline weight percent of above 60.89 % can effectively broaden the absorbing band with minimum absorption of 5 dB about 500 MHz. It has also been found that the composite with the polyaniline weight percent of 28.12 % has a maximum absorption of 23 dB at about 700 MHz for a coating thickness of 2 mm. Therefore, the prepared composites can be potentially applied in electromagnetic absorbing field in the low frequency.
This study showed the effect of Decabromodiphenylethane (DBDPE) - Sb2O3、Tetramomobisphenol A (BDDP) - Sb2O3 and Mg(OH)2 to the mechanical and retardant performance. To eliminate the bad influence of flame retardant agents to materials’ mechanical performance, SEBS-g-MAH and ABS-g-MAH were added into HIPS to toughen HIPS. The experimental results showed that Decabromodiphenylethane (DBDPE) - Sb2O3 had the best effect of flame retardant, and had little influence on the mechanical performance of HIPS. SEBS-g-MAH could improve the impact strength of HIPS greatly and had little influence on other performance.
This paper presents the design, development and characterization of the spinel ferrite [Mn0.2Zn0.8Fe2O4] powders and Nickel (Ni)-coated multiwall carbon nanotubes (MWNTs). A combination of Mn0.2Zn0.8Fe2O4 spinel ferrites particles and Nickel (Ni)-coated multiwall carbon nanotubes (MWNTs) were introduced into epoxy resin to be a microwave absorber. The structural characterizations and surface morphology of Mn0.2Zn0.8Fe2O4 and MWNTs were investigated by X-ray diffraction (XRD) and scanning electron microscopy respectively. The electromagnetic wave absorption characteristics of the composites have been studied in the frequency interval of 12-15GHz.The results for Mn0.2Zn0.8Fe2O4/EP, Mn0.2Zn0.8Fe2O4/MWNTs/EP and Mn0.2Zn0.8Fe2O4/Ni-coated MWNTs/EP microwave absorbers for the same thickness have been reported. It has been found that the Mn0.2Zn0.8Fe2O4/Ni-coated MWNTs/EP composites show the broadband characteristics with minimum absorption of 5 dB about 2.6 GHz and the maximum absorption of 37.05 dB at 14 GHz for a coating thickness of 2 mm. Therefore, Mn0.2Zn0.8Fe2O4/Ni-coated MWNTs/EP composites will be a suitable microwave absorptive material for 12-15GHz.
To solve the problems of low strength and high viscosity of room temperature vulcanized liquid silicone rubber, a series of terminated vinyl silicone oil were designed and synthesized, and low viscosity and high strength silicone rubber were prepared by the mechanical reinforcing agent. the results show that the molecular structure of the vinyl-terminated silicone oil has a significant effect on the mechanical properties and viscosity of the silicone rubber, and the best performance is found when the content of vinyl-terminated silicone oil is 0.16%. The low viscosity and high strength silicone rubber prepared from it was reinforced by vinyl MQ resin and fumed silica, which had a significant effect on improving the performance. Its tensile strength increased to 5.03 MPa, elongation at break to 338.90%, and tear strength to 7.15 kN/m compared to conventional silicone rubber, while the hardness increased to 43°. The viscosity is 34.9 Pa•s. The compression modulus is 7.48 MPa.
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