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A continuous-flow cavity ring-down spectroscopy (CRDS) system integrating a chromatographic separation technique, a catalytic combustor, and an isotopic 13 C/ 12 C optical analyzer is described for the isotopic analysis of a mixture of organic compounds. A demonstration of its potential is made for the geochemically important class of short-chain hydrocarbons. The system proved to be linear over a 3-fold injection volume dynamic range with an average precision of 0.95‰ and 0.67‰ for ethane and propane, respectively. The calibrated accuracy for methane, ethane, and propane is within 3‰ of the values determined using isotope ratio mass spectrometry (IRMS), which is the current method of choice for compound-specific isotope analysis. With anticipated improvements, the low-cost, portable, and easy-to-use CRDS-based instrumental setup is poised to evolve into a credible challenge to the high-cost and complex IRMS-based technique.cavity ring-down spectroscopy ͉ combustion ͉ isotopic ratio

High-resolution millimeter wave spectroscopy and multichannel quantum defect theory of the hyperfine structure in high Rydberg states of molecular hydrogen The fundamental rotational interval of para-H have been measured in the range 1-7.4 THz using a laser-based, pulsed, narrow-band source of submillimeter-wave radiation. The analysis of the spectra by multichannel quantum-defect theory (MQDT) has allowed a complete interpretation of the fine structures of the Rydberg series and their dependence on the principal quantum number. The extrapolation of the series to their limits with MQDT has enabled the determination of the first rotational interval of para-H

Mid-infrared radiation near 2.8 mum was generated by difference-frequency generation in an 80-mm-long periodically poled Ti:LiNbO(3) channel waveguide by pump radiation near 1.55 mum (tunable external-cavity laser) and a signal radiation of 3.391 mum (HeNe laser). We obtained a normalized conversion efficiency of 105% W(-1) , which is to our knowledge the highest value ever reported.

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