No abstract

Abstract:The reaction of wollastonite (CaSiO 3 ) with CO 2 in the presence of aqueous solutions (H 2 O) and varied temperature conditions (296 K, 323 K, and 333 K) was investigated. The educts (CaSiO 3 ) and the products (CaCO 3 and SiO 2 ) were analyzed by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD), and differential scanning calorimetry with thermogravimetry coupled with a mass spectrometer and infrared spectrometer (DSC-TG/MS/IR). The reaction rate increased significantly at higher temperatures and seemed less dependent on applied pressure. It could be shown that under the defined conditions wollastonite can be applied as a cementitious material for sealing wells considering CCS applications, because after 24 h the degree of conversion from CaSiO 3 to CaCO 3 at 333 K was very high (>90%). As anticipated, the most likely application of wollastonite as a cementitious material in CCS would be for sealing the well after injection of CO 2 in the reservoir.

Triaxial shear tests on mudstone samples from the Shimanto Belt and the Boso accretionary complexes (SW Japan and central Japan) were carried out. Pre-exhumation burial depths in the two paleo-accretionary prisms were up to 9,000 m and about 1,000 m for the Shimanto and the Boso samples, respectively. Three methods were applied: (1) pressure stepping tests at increasing confining pressures between 25 and 65 MPa and pore pressures between 20 and 52 MPa; (2) constant confining pressure tests at 55 and 65 MPa, with stepwise pore pressure decrease from 80% to 50% and 25%, and from 90% to 60% and 30% of the confining pressure; and (3) a cyclic loading test on one sample from Boso (19 cycles to 70-MPa differential stress). After some contraction due to pressurization in the first cycles, the sample showed tendencies to creep rather than to fracture. Effective shear parameters show that angles of internal friction between 30°and 50°are in part quite high in both sample subsets, and ranges of cohesion are between about 2 and 6 MPa (Boso) and 13 and >30 MPa (Shimanto). The mechanical results from these paleo-accretionary prisms are taken to constrain the shear parameters of rocks in the deeper parts of the present Nankai accretionary wedge and forearc. Static friction resembles results from experiments on a wide range of phyllosilicate-quartz-feldspar gouges and shows that the forearc is composed of relatively strong rock. Cohesion increase due to diagenesis and/or very low grade metamorphism is of overriding importance and probably permits stresses of up to 18 MPa to be transmitted to the updip end of the seismogenic zone at depth and 5 to 13 MPa to the backstop of the actively deforming frontal prism.

No abstract

No abstract