Figure 7. ESR spectra of PVP-1: (a) UV irradiated at 298 K and measured at 77 K; (b) UV irradiated at 77 K, heated to 298 K, and measured at 77 K. polymers (PVP-2 and PVP-3) produced from electrochemical and photoelectrochemical methods had the characteristics of the polymer (PVP-1) synthesized with Ziegler-Natta catalyst. Visible-light-induced photoelectrochemical polymerization has been reported for the first time at a n-GaAs semiconductor electrode.
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