Dioxouranium(VI) carboxylate polymers: synthesis and characterization of tractable coordination polymers and evidence for rigid rod conformation

Hardiman, Christopher J.; Archer, Ronald D.

doi:10.1021/ma00173a015

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Cited by 5 publications

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“…The synthesis and characterization of the uranyl dicarboxylates is detailed elsewhere Hardiman 1987 The molecular weights have been determined by GPC, viscosity, and NMR end-group analysis. Solid-state 13 C-NMR has also been used to confirm the coordination modes of the carboxylate ligands to the uranyl ion.…”

Section: Discussionmentioning

confidence: 99%

Photochemistry and Photophysics of Coordination Compounds

Yersin¹,

Vogler²

1987

156

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Section: Discussionmentioning

confidence: 99%

Photochemistry and Photophysics of Coordination Compounds

Yersin¹,

Vogler²

1987

156

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The characterization of the halatopolymers: A review

Ibidapo

1996

Polymer Engineering & Sci

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Halatopolymers belong to a group of ion‐containing materials that display both salt‐ and polymer‐like properties. Their mode of synthesis and other characteristics have been widely reported. This work considers the various reports as defined by both polymeric structure and by the metal ions involved in formation. Also provided are data on other characteristics by which this group of materials can be identified. Synthesis of simple nonpolymeric backbone structures can give highly crystalline salts, which become more amorphous after thermal treatment. While the polymeric backbone‐structured halatopolymers are soluble, the nonpolymeric backbone counterparts are generally insoluble. The halatopolymers exhibit relatively high thermal stabilities.

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The effects of varied reactant ratios on the polymeric structures of stannous dicarboxylates

Ibidapo

McIntyre

East

1991

Polymer Engineering & Sci

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Some polymeric Sn(II) dicarboxylates have been produced with good yields from aqueous solution via a double decomposition reaction using varied nonstoichiometric molar proportions of the reactants. They were obtained as highly viscous pale yellow liquids formed into separate denser phases in the precipitation bath. The highly viscous precipitates were drawn directly into fibers. Meltspun polymeric stannous dicarboxylates produced fibers which were only flexible above the glass transition temperature, Tg. When the aliphatic dicarboxylic acids were replaced with their aromatic counterparts similar highly viscous liquids were obtained, but they solidified almost at the instant of formation.

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Dioxouranium(VI) carboxylate polymers: synthesis and characterization of tractable coordination polymers and evidence for rigid rod conformation

Cited by 5 publications

References 6 publications

Photochemistry and Photophysics of Coordination Compounds

Photochemistry and Photophysics of Coordination Compounds

The characterization of the halatopolymers: A review

The effects of varied reactant ratios on the polymeric structures of stannous dicarboxylates

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