Photoinduced electron transfer (PET) between donors and acceptors in porous materials is a key element in the development of light harvesting applications. Metal organic frameworks (MOFs) are ideal materials for PET processes due to their tunable pore size and diversity in framework building units. Here, PET between excited [Ru(2,2'-bipyridine)3]2+ (RuBpy) and Co-carboxylate clusters composing the metal building blocks of a RWLC-2 metal organic framework is described. The lifetime of the RuBpy decreases from ∼600 ns in deaerated solution to 9.5 ns (kET ∼ 1 × 108 s-1) when encapsulated within CoRWLC-2. The decrease in lifetime is attributed to PET between the 3MLCT of RuBpy to the Co ion cluster composing the MOF building blocks. A fit of the lifetime vs. temperature data to the semi-empirical Marcus equation gives a reorganizational energy of 1.6 eV and an electronic coupling factor (HAB) of 0.006 eV.

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Amoxicillin, used to manage bacterial infection, is among the top five popular pharmaceuticals in the United States, based on the number of prescriptions. Problems with environmentally available drugs can arise chiefly; biological resistance in excess amounts becomes available in wastewater samples. Previously, we observed that Amoxicillin could be removed quantitatively from deionized water by passage over Octolig®, a polythylenediimine covalently attached to high-surface-area silica gel. This study was concerned with testing the potential removal of Amoxicillin in different solutions (tap water, well water, river water, and the weakly saline water). These solutions were passed over chromatography columns at a rate of 10 mL per minute; 50-mL fractions were collected and analyzed for total dissolved solids and pH as well as concentration. As noted in our previous work, the percentage removal was related to the length of the column, and this aspect was evaluated again. Consistent results were obtained for DI water, tap water, well water, and river water, indicating quantitative removal, and but not artificial bay water, presumably because of ion competition.

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