Hydrogen delivery is a critical contributor to the cost, energy use and emissions associated with hydrogen pathways involving central plant production. The choice of the lowest-cost delivery mode (compressed gas trucks, cryogenic liquid trucks or gas pipelines) will depend upon specific geographic and market characteristics (e.g. city population and radius, population density, size and number of refueling stations and market penetration of fuel cell vehicles). We developed models to characterize delivery distances and to estimate costs, emissions and energy use from various parts of the delivery chain (e.g. compression or liquefaction, delivery and refueling stations). Results show that compressed gas truck delivery is ideal for small stations and very low demand, liquid delivery is ideal for long distance delivery and moderate demand and pipeline delivery is ideal for dense areas with large hydrogen demand. ᭧

a b s t r a c tThis paper investigates how California may reduce transportation greenhouse gas emissions 80% below 1990 levels by 2050 (i.e., 80in50). A Kaya framework that decomposes greenhouse gas emissions into the product of population, transport intensity, energy intensity, and carbon intensity is used to analyze emissions and mitigation options. Each transportation subsector, including light-duty, heavy-duty, aviation, rail, marine, agriculture, and off-road vehicles, is analyzed to identify specific mitigation options and understand its potential for reducing greenhouse gas emissions. Scenario analysis shows that, while California's 2050 target is ambitious, it can be achieved in transport if a concerted effort is made to change travel behavior and the vehicles and fuels that provide mobility. While no individual ''Silver Bullet" strategy exists that can achieve the goals, a portfolio approach that combines strategies could yield success. The 80in50 scenarios show the impacts of advanced vehicle and fuels technologies as well as the role of travel demand reduction, which can significantly reduce energy and resource requirements and the level of technology development needed to meet the target.

▪ Abstract  This chapter on fuel cells covers the following topics: (a) fundamental electrochemical aspects and performance analysis; (b) technology research and development and demonstrations of fuel cell power sources for power generation, transportation, portable power, and space applications; (c) the role of fuel cells vs competing technologies, and (d) prospects for the applications and commercialization of fuel cell technologies in the twenty-first century. Although the fuel cell was invented in the nineteenth century, the twentieth century has been the period for technology development rather than widespread use. The fuel cell faces a great deal of competition in the proposed applications of power generation, transportation, and portable power. Significant work is still necessary, but intensified research and development activities could lead to the dawn of fuel cell commercialization and widespread use in the early part of the twenty-first century.

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