Single and multiphoton absorptions in wide band gap semiconductors
determine the functionality of photodetectors, lasers, and light-emitting
diodes (LEDs). Although electronic structure strongly influences the
different orders of multiphoton absorptions in semiconductors, it
has not been feasible to quantify their contributions on the functionality
of devices. A lack of proper measurement techniques has been the hurdle.
Here, we present a simple and sensitive method based on the phase
modulation of femtosecond pulses to quantify single-, two-, and three-photon
absorptions in GaP and InGaN photodetectors. Our results show that
only three-photon absorption contributes to the photocurrent in the
InGaN device when excited by femtosecond pulses at 1030 nm. On the
other hand, single-, two-, and three-photon absorptions have comparable
contributions in the GaP detector. The three contributions have different
origins: linear photocurrent is attributed to the absorption by the
impurities in the doped regions, two-photon photocurrent is from the
phonon-assisted indirect transition from the valence band to the conduction
band minimum, and three-photon photocurrent is from the direct transition
to the conduction band. We also demonstrate that the method can be
applied to image the heterogeneity of multiphoton photocurrent in
devices. Our work could be adapted for “in operando” characterization of optoelectronic systems.
The question of how to define the legal status of marine genetic resources (hereinafter MGRs) in areas beyond national jurisdiction (hereinafter ABNJ) is one of the important issues in the negotiation of the International Legally Binding Instrument under United Nations Convention on the Law of the Sea on the Conservation and Sustainable Use of Marine Biodiversity of Areas beyond National Jurisdiction. According to the theory of the order and justice value of the law, in combining the experiences of the international community in handling global ocean problems and characteristics of MGRs in ABNJ, it can be said that MGRs in ABNJ have the legal attribute of being the common heritage of mankind (hereinafter CHM). From the perspective of the principle of CHM, in applying the subject, object and content elements of legal relations as the research approach, the legal status of MGRs in ABNJ should be defined as follows: Firstly, an international management body should be established and the scope of actual resource developers should be defined in terms of subject elements. Secondly, the temporal scope, geographical scope and material scope of MGRs in ABNJ should be clarified in terms of object elements. Thirdly, the disposition of rights and obligations in the process of development and utilization of MGRs in ABNJ should be defined in terms of content elements.
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