With the continuous development of society, the pressure of human beings is increasing, and the problem of psychological counseling for school students is getting more and more serious, which has brought great challenges to the education and management of school students. Universities should cultivate students’ professional ability on knowledge and practical skills; we should pay more attention to their psychological counseling and develop and design a simple and efficient learning environment. It is very necessary to establish a psychological evaluation system for college students. This article is based on the design and application of the mobile education information system for psychological education. It highlights that the current psychological counseling problems in school education are indispensable. To better manage the psychological counseling problems faced by many students, 67% of the students have many psychological problems, and the mental health of students in school education and psychological counseling have become the common concern and urgent problems of all college managers. This paper uses the methods of literature research, behavior interview, and experimental investigation to investigate the complementary relationship between the connotation of education and psychological counseling from the data of the fuzzy integral model of psychological counseling, so as to pay more attention to the students’ mental health problems and make the students grow up healthily. The experimental results of this article show that there is still a lot of room for improvement in the use of mobile education information systems to improve their ability to carry out psychological counseling work.

Education has improved the ideological style of society, improved people’s spiritual quality, and improved people’s lifestyle, provided sincere principles for people’s enthusiasm, and provided goals and political power for people’s ideals and contemporary thinking. Thinking diagrams are a teaching method that helps people sort out their ideas and solve difficult problems and can clearly connect the relationships between various concepts. This article is intended to explore the auxiliary effects of case analysis and thinking in psychological education in the context of mobile new systems. Through a series of research methods such as literature research method, action research method, mathematical statistics method, etc., finally 110 elementary and middle school students with psychological problems in a city conducted an experimental survey, and SPSS software was used to analyze and research the statistical results. The experimental results of this article show that psychological teachers use mental icons to provide psychological counseling to students with psychological problems. The success rate of counseling can be increased by 5–10%. It can be seen that an effective method of thinking diagram education can promote the better development of students, and it can also help more teenagers with psychological problems to get rid of psychological barriers.