This paper presents an experimental lab designed for undergraduate students which focuses on soil science and chemistry. Students perform a series of tests to classify soil's phosphate retaining characteristics, texture, pH, organic matter content, and permeability with the addition of a novel soil amendment, Al Mg biochar. This lab has minimal cost as most chemicals are inexpensive and a soil column is crafted from a used water bottle, filter paper, and masking tape. Students apply their measurements to understand how agriculture plays a role in ocean and watershed health and how soil-testing, soil amendments, and responsible farming practices can minimize agriculture's footprint. It is important for agriculturally focused students to understand how soil chemistry relates to crop yields, and the importance of responsible agricultural practices. Learning outcomes and student attitudes from this experiment were assessed to evaluate the experiment.
Slag and Al/Mg oxide modified Douglas fir biochar (AMOB) were compared for their phosphate adsorbing abilities for use individually or in combination for simulated agriculture run-off remediation in wetlands. Aqueous batch and column sorption experiments were performed for both low-cost materials. AMOB was prepared in bulk using a novel green method. Material analyses included XRD, elemental analysis, SEM, EDX, and BET. Biochar and slag have different phosphate removal mechanisms. In short residence times (≤2 h), adsorption phenomena dominate for both adsorbents. Surface area likely plays a role in adsorption performance; slag was measured to be 4.1 m2/g while biochar’s surface area was 364.1 m2/g. In longer residence times (>2 h), the slow leaching of metals (Ca, Al, and Mg) from slag continue to remove phosphate through the precipitation of metal phosphates. In 24 h, slag removed more free phosphate from the solution than AMOB. Preliminary fixed bed column adsorption of slag or AMOB alone and in tandem was performed adopting a scaled-up model that can be used to remediate agricultural runoff with high phosphate content. Additionally, a desorption study was performed to analyze the efficiency of material regeneration. While AMOB does not release any adsorbed phosphates, slag slowly releases 5.7% adsorbed phosphate over seven days.
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