A novel design is presented for a nanowire/polymer hybrid photodiode. n-InP nanowires are grown directly onto an indium tin oxide (ITO) electrode to increase carrier collection efficiency and to eliminate the need for an expensive substrate. Experiments show that an ohmic contact is achieved between the nanowires and the ITO electrode. The nanowires are then enveloped by a high hole mobility conjugated polymer, poly(3-hexylthiophene). Compared to the control polymer-only device, the inclusion of InP nanowires increases the forward bias current conduction by 6-7 orders of magnitude. A high rectification ratio of 155 is achieved in these photodiodes along with a low ideality factor of 1.31. The hybrid device produces a photoresponse with a fill factor of 0.44, thus showing promise as an alternative to current polymer solar cell designs.

Vertically-aligned InP nanowires are grown by metalorganic chemical vapor deposition (MOCVD) without the use of a deposited metal catalyst. A surface reconstruction induces indium droplets to form on the surface and thus act as nucleation sites for nanowire growth. Vertical growth from the InP(111)B substrate along with transmission electron microscopy (TEM) analysis indicate epitaxial growth from the substrate in the [111]B direction. A uniform cross section along the longitudinal axis can be achieved by optimizing the input V∕III ratio. Small variations in the diameter and length are seen under optimal growth conditions.

A novel fabrication procedure is developed that allows for the direct measurement of the linear electrooptic coefficient of semiconducting nanowires to determine their viability for use in electrooptic devices. Vertically aligned InP nanowires are transferred from their growth substrate to a glass substrate using a host polymer, while still retaining the alignment of the nanowires. The linear electrooptic coefficient of the InP nanowires exhibited a 1-2 orders of magnitude enhancement over bulk InP and ranged from 31 to 147 pm/V. The figure of merit, n3r, exhibited a factor of 20 enhancement over lithium niobate and ranged from 1010 to 4817 pm/V.