Recently, the application of polymer-based composites at cryogenic conditions has become a hot topic, especially in aerospace fields. At cryogenic temperature, the polymer becomes more brittle, and the adverse effect of thermal stress induced by temperature is more remarkable. In this paper, the research development of thermoset and thermoplastic polymers for cryogenic applications are all reviewed. This review considers the literature concerning: (a) the cryogenic performance of modified thermoset polymers and the improving mechanisms of the reported modification methods; (b) the cryogenic application potential of some commercial thermoplastic polymers and the cryogenic performance of modified thermoplastic polymers; (c) the recent advance in the use of polymer for special cryogenic environment-liquid oxygen. This paper provides a comprehensive overview of the research development of the polymer for cryogenic application. Moreover, future research directions have been proposed to facilitate its practical applications in aerospace.
In
order to develop a novel kind of antibacterial Cu-containing TiN film
with good corrosion resistance, impressive mechanical properties,
and low cytotoxicity, three differently designed multilayer films
of TiCu/TiCuN multilayer (M1, M2, M3) were deposited on the surface
of 316L stainless steel surface using the axial magnetic field-enhanced
arc ion plating (AMFE-ARP) method, in which the interlayer of TiCu
was first introduced for Cu-containing TiN film in order to improve
comprehensive properties, especially the corrosion resistance of the
film. The performance of the TiCu/TiCuN multilayer films was compared
with that of the two single layers, TiN and TiCuN, which were deposited
by the same method and the same total deposition time. The results
indicated that the TiCu/TiCuN multilayer film of M2 revealed the best
comprehensive corrosion resistance with low electric current values,
high pitting potential, and high polarization resistance due to the
proper thickness of TiCu interlayers and larger number of TiCu/TiCuN
bilayers. In addition, the TiCu/TiCuN multilayer film of M2 also possesses
comparable mechanical properties, excellent antibacterial and antibiofilm
abilities, as well as good biocompatibility. Consequently, the antibacterial
TiCu/TiCuN multilayer films with good corrosion resistance deposited
by using the axial magnetic field-enhanced arc ion plating (AMFE-ARP)
method are promising for application in biomedical antibacterial film
for implants.
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