Generally speaking, the preparation of single-atom catalysts always requires harsh conditions such as high-temperature pyrolysis or strong acid etching. In this manuscript, a simple and effective plasma-activated strategy is employed...

The species composition and abundance of the planktonic Hyperiidea and their relationship with environmental factors (depth, temperature, salinity, dissolved oxygen, turbidity and chlorophyll a concentration) were analyzed based on 4 seasonal investigations in the Beibu Gulf between 2006 and 2007. Hyperiids were represented by 82 species, 5 of which had not previously been recorded in the South China Sea. The hyperiid communities were dominated by Lestrigonus bengalensis year-round, Hyperioides sibaginis was dominant in spring, summer and autumn, and Tullbergella cuspidata became dominant in spring. Both species richness and the Shannon-Wiener diversity index increased from north to south, and from nearshore to offshore. Biodiversity was higher in some regions where the water mass was strongly influenced by the open sea or the lower salinity water off the northern sea shelf. Results of partial correlation analysis showed that species richness was positively related to depth at all times, and negatively related to temperature only in summer and winter. TWINSPAN classification indicated that the Hyperiidea community was divided into 2 groups in spring and winter (a widely distributed group and a pelagic warm-water group), and 3 groups in summer and autumn. A clear distinction between euryhaline and pelagic species can be discerned, based on different geographical distributions of water masses.

Bimetallic materials are one of the most promising catalysts for the electrochemical reduction of CO2, but there are still many challenges to be overcome on the route to industrialization. Herein, a series of carbon nanofiber-supported bimetallic cobalt–copper catalysts (CoxCuy/CFs) are designed and constructed through the electrospinning technique and a subsequent pyrolysis procedure. Small-sized Co–Cu nanoparticles are homogenously distributed on the porous carbon nanofibers, which can significantly improve the utilization rate of metal sites and greatly reduce the loading amount of metals. Moreover, different product distributions and catalytic performance can be obtained in CO2 reduction via adjusting the metal proportion of CoxCuy/CFs. Especially, Co3Cu/CFs can bring forth a 97% total faradaic efficiency (FE) of CO (68%) and HCOOH (29%) at –0.8 VRHE cathode potential in 0.5 M KHCO3 electrolyte. Furthermore, the hierarchical pores can firmly confine the small Co–Cu nanoparticles and keep them from easy agglomeration during electrolysis, eventually leading to 60 h of stability for Co3Cu/CFs in CO2 electroreduction. This study might provide a facile and economic method to fabricate efficient bimetallic catalysts for CO2 electroreduction and other electrocatalysis applications.

No abstract