The degradability and processability of new renewable materials based on starch and PVOH were studied using the melt flow index (MFI) method by measuring the melt rheological properties which depend not only on the extrusion conditions and material formulation but also on the macromolecule characteristics which can be modified by chemical degradation. These results were correlated with other material properties like color and cross-linking degree. The obtained results show that flowing in the melted state of the studied materials is accompanied by a second process of chains chemical degradation. It was observed that, at the same level of additivation, under identical extrusion conditions, the melted blends with corn starch as main component are highly mechanically sensitive and degrade mostly by chains scission and those with PVOH as major component are highly temperature sensitive and degrade mainly by cross-linking. The obtained results show also that each PVOH-starch blend requires particular formulation and individual windows of melt processing conditions. These results are a good proof that the MFI method is a good path to study the degradability and moldability of process sensitive polymeric materials like those based on starch and PVOH.
In this paper is analysed the air quality in urban areas in Bucharest, the analysis was based on the monitoring of the average concentration of particulate matter PM 10, nitrogen oxides, NO2, and sulfur dioxide, SO2 in Bucharest between 2009-2015. The analysis refers to the maximum concentration of 24 h and the occurrence of overruns beyond the limit set. It also looked at the wind regime, air quality and temperature influence on air pollution in Bucharest between 2009-2015.
In this paper, optimum hot formation processing parameters for 31VMn12 steel were established, the torsion deformation of 31VMn12 steel was investigated at temperatures from 900, 1000, 11000C and strain rates from 0.05 s-1 to 3 s. -1. There were studied the structural aspects of materials, in microstructures by electronic microscopy. The stress level decreases with increasing deformation temperature and decreasing strain rate, which can be represented by a Zenner-Hollomon parameter. The mathematical model presented in the paper describes the relationship of tension strain, voltage and temperature coefficient 31VMn12 steel at high temperatures. The stress-strain curves determined by the torsion test allowed the calculation of the Zenner-Hollomon parameter corresponding to the maximum stress. By using this parameter has established a set of equations that reproduce completely stress-strain curve, including the hardening, the restoration and dynamic recrystallization area. Comparisons were made between the experimental results and the predicted and confirmed that constitutive equations developed can be used for mathematical modelling and other attempts (forging, compression) and other types of steel.
Present paper has as objective the experimental study regarding the study on the dynamic parameters of modified fluidized bed. For the granular biomaterial processing by drying there are necessary intensifications techniques to avoid the thermal degradation. Present paper propose as intensification technique the modified fluidized bed (or flotation �fluidized bed) in which the granular biomaterial is mixed with inert material of small sizes. The purpose is to obtain the better dynamic conditions for the drying process.
In this paper we analyze the influence of the number of laser pulses on the hardness of the metal. We have shown that the hardness increases with the number of laser pulses due to the increase in the probe surface temperature, especially by increasing the superficial absorption of laser radiation. Optical microscopy was analyzed by the metallographic aspects of the target in OLT 65, Al, Cu, laser irradiated.
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