The possibility of preparing molding-bioengineered materials, such as woodchip boards (WCB), from sawdust using technical lignosulfonate (LGS), a wood waste product, and a culture liquid (CL) of levan microbial polysaccharide producer by Azotobacter vinelandii D-08 is explored in this article. The parameters of the derived materials are comparable to those of traditional materials made from toxic phenol-formaldehyde resins. The various physical and mechanical characteristics of the materials depend on the quantity of the bonding agent used for the preparation. Adding a culture liquid increases the humidity resistance of the molding materials. Using electron microscopy and X-ray microtomography, it is clear that the structure of woodchip boards become more homogeneous without microcracks with the addition of CL. The strength of the best samples prepared was approximately 24 to 29 MPa with a density of 1170 to 1255 kg/m 3 and a swell on wetting of 6.7%. During hot pressing, noticeable changes were observed by Fourier transform infrared spectroscopy (FTIR) at frequencies typical of LGS sulfonic-acid groups, levan fructose fragments, and skeletal vibrations of a syringal/guaiacyl core in lignin and of C-H groups of hemicelluloses. This indicates the involvement of these functional groups in the process of binding wood particles with hot pressing.
Pressed composites can be produced from wood sawdust waste using modified yeast biomass, waste as a bio-adhesive, ultra-dispersed bacterial cellulose (UBC) as a binder, and preliminary chemical crosslinking. The materials obtained were not inferior to traditional materials based on the required levels of toxic phenol-formaldehyde resin and physical and mechanical parameters. Physical and mechanical properties of the materials depended on the amount and viscosity of the binder, as well as on the chemical structure and conditions of chemical cross-linking and modified UBC application. The strengths of the best examples of the materials obtained were approximately 17 to 20 MPa, the densities were in the range of 1207 to 1255 kg/m 3 , and the water absorption was less than 20%. During hot pressing, notable changes were observed in the wood particles at FTIR-ATR spectra frequencies of 3620 cm -1 , 3600 to 3000 cm -1 , 2920 cm -1 , 2850 cm -1 , 1770 cm -1 , 1650 cm -1 , 1560 cm -1 , and 1089 cm -1 . This is mainly due to the chemical and structural changes in lignin, hemicellulose, and binder.
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