Abstract. Spatio-temporal variations in the partial pressure of CO2 (pCO2)
were studied during eight oceanographic cruises conducted between March 2014 and
February 2016 in surface waters of the eastern shelf of the Gulf of
Cádiz (SW Iberian Peninsula) between the Guadalquivir river and Cape
Trafalgar. pCO2 presents a range of variation between 320.6 and 513.6 µatm with highest values during summer and autumn and lowest during
spring and winter. For the whole study, pCO2 shows a linear dependence
with temperature, and spatially there is a general decrease from coastal to
offshore stations associated with continental inputs and an increase in the
zones deeper than 400 m related to the influence of the eastward branch of
the Azores Current. The study area acts as a source of CO2 to the
atmosphere during summer and autumn and as a sink in spring and winter with
a mean value for the study period of -0.18±1.32 mmol m−2 d−1. In the Guadalquivir and Sancti Petri transects, the CO2 fluxes decrease towards offshore, whereas in the Trafalgar transect fluxes
increase due to the presence of an upwelling. The annual uptake capacity of
CO2 in the Gulf of Cádiz is 4.1 Gg C yr−1.
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