Efficient photocatalytic nanocrystals with high-ratio exposure of active facets have aroused a great number of research interests in recent years. However, most preparations of such materials need the addition of special capping agents (like surfactants) or harsh reaction conditions (such as hydrothermal reactions). In this work, a controllable synthesis of BiOBr nanosheets with a thickness from 9 nm to 32 nm was easily achieved in a hydrolysis system through adjusting temperature and solvent, without adding any surfactant or capping agents. As the thickness of the nanosheets decreases from 32 nm to 9 nm, the ratio of exposed {001} facets, the active photocatalysis facets in BiOBr crystals, increases from 83% to 94%, along with an increased photocatalytic efficiency over rhodamine B (RhB) under visible-light.Various methods such as SEM, TEM, AFM, DRS and Raman spectroscopy were used to fully characterize the as-obtained BiOBr nanosheets. More importantly, the obtained BiOBr nanosheets exhibit a selective visible-light photocatalytic behavior as the activity over RhB is much higher than that over Methyl Orange (MO) or Methylene Blue (MB). This phenomenon was studied with in situ electron paramagnetic resonance (EPR) measurements and the potential mechanism was explored.
The proliferation of wireless localization technologies provides a promising future for serving human beings in indoor scenarios. Their applications include real-time tracking, activity recognition, health care, navigation, emergence detection, and target-of-interest monitoring, among others. Additionally, indoor localization technologies address the inefficiency of GPS (Global Positioning System) inside buildings. Since people spend most of their time in indoor environments, indoor tracking service is in great public demand. Based on this observation, this paper aims to provide a better understanding of state-of-the-art technologies and stimulate new research efforts in this field. For these purposes, existing localization technologies that can be used for tracking individuals in indoor environments are reviewed, along with some further discussions.
Since ancient times, people have used photosynthesized wood, bamboo, and cotton as building and clothing materials. The advantages of photo polymerization include the mild and easy process. However, the direct use of available sunlight for the preparation of materials is still a challenge due to its rather dilute intensity. Here, we show that semiconductor nanoparticles can be used for initiating monomer polymerization under sunlight and for cross-linking to form nanocomposite hydrogels with the aid of clay nanosheets. Hydrogels are an emerging multifunctional platform because they can be easily prepared using solar energy, retain semiconductor nanoparticle properties after immobilization, exhibit excellent mechanical strength (maximum compressive strength of 4.153 MPa and tensile strength 1.535 MPa) and high elasticity (maximum elongation of 2784%), and enable recyclable photodegradation of pollutants. This work suggests that functional nanoparticles can be immobilized in hydrogels for their collective application after combining their mechanical and physiochemical properties.
The mathematical model can represent the DIL∕DI∞ curve from a single axial CT scan. Generally, n ≠ 1. The equilibrium dose, α, n, and Leq exhibit strong dependencies on phantom diameter and location in the phantom. On the other hand, α, n, and Leq have relatively weak dependencies on material (PMMA or water), tube voltage (80-140 kVp), and bowtie filter, and Leq is also insensitive to beam width (≤4 cm). A weak dependency of the DIL∕DI∞ curve on CT scanner using 80-140 kVp and beam width up to 4 cm is consistent with the results of this study and previous publications. The dose equilibration data provided in this paper can be useful for CT dose evaluation. A framework is presented for assessing dose at any point in infinitely long PMMA and water cylinders undergoing multidetector CT examinations.
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