BackgroundRelatively inexpensive, stable Schiff bases, namely 3-((4-hydroxybenzylidene)amino)-2-methylquinazolin-4(3H)-one (BZ3) and 3-((4-(dimethylamino)benzylidene)amino)-2-methylquinazolin-4(3H)-one (BZ4), were employed as highly efficient inhibitors of mild steel corrosion by corrosive acid.FindingsThe inhibition efficiencies were estimated based on weight loss method. Moreover, scanning electron microscopy was used to investigate the inhibition mechanism. The synthesized Schiff bases were characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy and micro-elemental analysis. The inhibition efficiency depends on three factors: the amount of nitrogen in the inhibitor, the inhibitor concentration and the inhibitor molecular weight.ConclusionsInhibition efficiencies of 96 and 92% were achieved with BZ4 and BZ3, respectively, at the maximum tested concentration. Density functional theory calculations of BZ3 and BZ4 were performed to compare the effects of hydroxyl and N,N-dimethylamino substituents on the inhibition efficiency, providing insight for designing new molecular structures that exhibit enhanced inhibition efficiencies.

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This study included estimating the heavy elements of some types of grape juice of different origin and determining their proportions in juices and comparing them with the quality control of Iraq and observing whether it is suitable for human use or not. Calcium salts are observed as 137 ppm in C juice and 9.5 ppm of magnesium in juice B, for heavy metals the highest percentage of lead 0.19ppm recorded in juice A, 1.7 ppm of copper in B juice 3.5 ppm Iron in juice A, 0.8 ppm of zinc in B juice and A, 0.06 ppm of aluminum in B, 0.015 ppm of cobalt in juice A and B, 0.06 ppm of nickel in B juice, Sodium was 168.1 ppm in C juice, but the acids were found to have the highest rates were 3.1 ppm of malic acid in B, 156.7 ppm of acid in Juice of ascorbic B, 238.5 ppm of acid found in lemon juice 130ppm in juice B.

In this research, the actions of antibiotic trimethoprim alone and with metals combained. Then assayed through formation of base transition metal compounds as ligands have the chance to achieve an unusual arrangement and stability complexes of coordination. We show advancement in using transtional metal compounds medications for treamentt manyl human illnesses such as carcinomas, lymphomas, control of infections, anti-inflammatory disorders, diabetes, with neurological conditions. This combination with transition metal observed the interaction can be separated by derivative spectroscopic method and measure the characterization of compound by IR and UV spectroscopy.